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Metals in Biotechnology: Cr‐Driven Stereoselective Reduction of Conjugated C=C Double Bonds
Elemental metals are shown to be suitable sacrificial electron donors to drive the stereoselective reduction of conjugated C=C double bonds using Old Yellow Enzymes as catalysts. Both direct electron transfer from the metal to the enzyme as well as mediated electron transfer is feasible, although th...
Autores principales: | Rauch, Marine C. R., Gallou, Yann, Delorme, Léna, Paul, Caroline E., Arends, Isabel W. C. E., Hollmann, Frank |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217005/ https://www.ncbi.nlm.nih.gov/pubmed/31713969 http://dx.doi.org/10.1002/cbic.201900685 |
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