Cargando…

Selective Acceptorless Dehydrogenation of Primary Amines to Imines by Core–Shell Cobalt Nanoparticles

Core–shell nanocatalysts are attractive due to their versatility and stability. Here, we describe cobalt nanoparticles encapsulated within graphitic shells prepared via the pyrolysis of a cationic poly‐ionic liquid (PIL) with a cobalt(II) chloride anion. The resulting material has a core–shell struc...

Descripción completa

Detalles Bibliográficos
Autores principales:	Cui, Xinjiang, Li, Wu, Junge, Kathrin, Fei, Zhaofu, Beller, Matthias, Dyson, Paul J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217016/ https://www.ncbi.nlm.nih.gov/pubmed/32049401 http://dx.doi.org/10.1002/anie.201915526

Ejemplares similares

Acceptorless dehydrogenation and hydrogenation of N- and O-containing compounds on Pd(3)Au(1)(111) facets
por: Cui, Xinjiang, et al.
Publicado: (2020)

Cobalt‐Catalyzed Aqueous Dehydrogenation of Formic Acid
por: Zhou, Wei, et al.
Publicado: (2019)

Facile synthesis of amides via acceptorless dehydrogenative coupling of aryl epoxides and amines
por: Liang, Yaoyu, et al.
Publicado: (2022)

Iron-based nanocatalyst for the acceptorless dehydrogenation reactions
por: Jaiswal, Garima, et al.
Publicado: (2017)

Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium
por: Zou, You-Quan, et al.
Publicado: (2020)

Identification of active catalysts for the acceptorless dehydrogenation of alcohols to carbonyls
por: Wang, Tao, et al.
Publicado: (2021)

Reduced Graphene Oxides as Carbocatalysts in Acceptorless Dehydrogenation of N-Heterocycles
por: Mollar-Cuni, Andrés, et al.
Publicado: (2021)

Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia
por: Luo, Jie, et al.
Publicado: (2022)

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis
por: West, Julian G., et al.
Publicado: (2015)

Metal-free carbocatalyst for room temperature acceptorless dehydrogenation of N-heterocycles
por: Hu, Haitao, et al.
Publicado: (2022)

Acceptorless Dehydrogenation of Methanol to Carbon Monoxide and Hydrogen using Molecular Catalysts
por: Kaithal, Akash, et al.
Publicado: (2021)

Cobalt Single‐Atom Catalysts with High Stability for Selective Dehydrogenation of Formic Acid
por: Li, Xiang, et al.
Publicado: (2020)

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes
por: McKay, Alasdair I., et al.
Publicado: (2019)

Selective Oxidation of Glycerol via Acceptorless Dehydrogenation Driven by Ir(I)-NHC Catalysts
por: Jiménez, M. Victoria, et al.
Publicado: (2022)

On the mechanism of acceptorless dehydrogenation of N-heterocycles catalyzed by (t)BuOK: a computational study
por: Ma, Lishuang, et al.
Publicado: (2023)

Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles
por: Taniguchi, Kento, et al.
Publicado: (2017)

A General Catalyst Based on Cobalt Core–Shell Nanoparticles for the Hydrogenation of N‐Heteroarenes Including Pyridines
por: Murugesan, Kathiravan, et al.
Publicado: (2020)

Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions
por: de Boer, Sandra Y., et al.
Publicado: (2017)

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes
por: Daw, Prosenjit, et al.
Publicado: (2018)

Efficient acceptorless photo-dehydrogenation of alcohols and N-heterocycles with binuclear platinum(ii) diphosphite complexes
por: Zhong, Jian-Ji, et al.
Publicado: (2019)

Preparation and Degradation of Rhodium and Iridium Diolefin Catalysts for the Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols
por: Buil, María L., et al.
Publicado: (2021)

Visible-Light-Promoted Iridium(III)-Catalyzed Acceptorless Dehydrogenation of N-Heterocycles at Room Temperature
por: Mejuto, Carmen, et al.
Publicado: (2022)

Direct synthesis of amides and imines by dehydrogenative homo or cross-coupling of amines and alcohols catalyzed by Cu-MOF
por: Anbardan, Soheil Zamani, et al.
Publicado: (2021)

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium
por: Daw, Prosenjit, et al.
Publicado: (2018)

Selective cobalt nanoparticles for catalytic transfer hydrogenation of N-heteroarenes
por: Chen, Feng, et al.
Publicado: (2017)

A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
por: Andérez‐Fernández, María, et al.
Publicado: (2016)

Iron-Catalyzed Acceptorless Dehydrogenative Coupling of Alcohols With Aromatic Diamines: Selective Synthesis of 1,2-Disubstituted Benzimidazoles
por: Putta, Ramachandra Reddy, et al.
Publicado: (2020)

Chemo- and Regioselective Synthesis of Acyl-Cyclohexenes by a Tandem Acceptorless Dehydrogenation-[1,5]-Hydride Shift Cascade
por: Smith, Lewis B., et al.
Publicado: (2020)

Non-metal-mediated N-oxyl radical (TEMPO)-induced acceptorless dehydrogenation of N-heterocycles via electrocatalysis
por: Hou, Huiqing, et al.
Publicado: (2022)

Cyclometalated iridium complexes-catalyzed acceptorless dehydrogenative coupling reaction: construction of quinoline derivatives and evaluation of their antimicrobial activities
por: Shui, Hongling, et al.
Publicado: (2022)

Heterogeneously Catalyzed Selective Acceptorless Dehydrogenative Aromatization to Primary Anilines from Ammonia via Concerted Catalysis and Adsorption Control
por: Li, Hui, et al.
Publicado: (2023)

Catalytic Acceptorless Dehydrogenation (CAD) of Secondary Benzylic Alcohols into Value-Added Ketones Using Pd(II)–NHC Complexes
por: Al-Romaizan, Abeer Nasser, et al.
Publicado: (2023)

Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines
por: Cabrero-Antonino, Jose R., et al.
Publicado: (2016)

Homogeneous cobalt-catalyzed reductive amination for synthesis of functionalized primary amines
por: Murugesan, Kathiravan, et al.
Publicado: (2019)

Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp(3) carbons
por: Wu, Xuesong, et al.
Publicado: (2015)

A General Regioselective Synthesis of Alcohols by Cobalt‐Catalyzed Hydrogenation of Epoxides
por: Liu, Weiping, et al.
Publicado: (2020)

Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts
por: de Almeida, Leandro Duarte, et al.
Publicado: (2020)

A Selective and General Cobalt‐Catalyzed Hydroaminomethylation of Olefins to Amines
por: Yang, Ji, et al.
Publicado: (2021)

Lung toxicities of core–shell nanoparticles composed of carbon, cobalt, and silica
por: Al Samri, Mohammed T, et al.
Publicado: (2013)

Manganese Promoted (Bi)carbonate Hydrogenation and Formate Dehydrogenation: Toward a Circular Carbon and Hydrogen Economy
por: Wei, Duo, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_4e9qn894fr31411i47c7njah78