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Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg (.+) to CO(2) in [MgCO(2)(H(2)O)(n)](.+), n=0–8

We investigate activation of carbon dioxide by singly charged hydrated magnesium cations Mg (.+)(H(2)O)(n), through infrared multiple photon dissociation (IRMPD) spectroscopy combined with quantum chemical calculations. The spectra of [MgCO(2)(H(2)O)(n)](.+) in the 1250–4000 cm(−1) region show a sha...

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Detalles Bibliográficos
Autores principales:	Barwa, Erik, Pascher, Tobias F., Ončák, Milan, van der Linde, Christian, Beyer, Martin K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7217156/ https://www.ncbi.nlm.nih.gov/pubmed/32100953 http://dx.doi.org/10.1002/anie.202001292

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