First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides

An efficient method for the synthesis of tetraoxathiaspiroalkanes, tetraoxathiocanes, and hexaoxathiadispiroalkanes was developed by reactions of pentaoxacanes, pentaoxaspiroalkanes, and heptaoxadispiroalkanes with hydrogen sulfide in the presence of a catalyst, Sm(NO(3))(3)·6H(2)O. We found that th...

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Autores principales: Makhmudiyarova, Nataliya, Ishmukhametova, Irina, Dzhemileva, Lilya, D’yakonov, Vladimir, Ibragimov, Askhat, Dzhemilev, Usein
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7221664/
https://www.ncbi.nlm.nih.gov/pubmed/32325665
http://dx.doi.org/10.3390/molecules25081874
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author Makhmudiyarova, Nataliya
Ishmukhametova, Irina
Dzhemileva, Lilya
D’yakonov, Vladimir
Ibragimov, Askhat
Dzhemilev, Usein
author_facet Makhmudiyarova, Nataliya
Ishmukhametova, Irina
Dzhemileva, Lilya
D’yakonov, Vladimir
Ibragimov, Askhat
Dzhemilev, Usein
author_sort Makhmudiyarova, Nataliya
collection PubMed
description An efficient method for the synthesis of tetraoxathiaspiroalkanes, tetraoxathiocanes, and hexaoxathiadispiroalkanes was developed by reactions of pentaoxacanes, pentaoxaspiroalkanes, and heptaoxadispiroalkanes with hydrogen sulfide in the presence of a catalyst, Sm(NO(3))(3)·6H(2)O. We found that the synthesized S-containing di- and triperoxides exhibit high cytotoxic activity against Jurkat, K562, U937, and HL60 tumor cultures, and fibroblasts.
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spelling pubmed-72216642020-05-22 First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides Makhmudiyarova, Nataliya Ishmukhametova, Irina Dzhemileva, Lilya D’yakonov, Vladimir Ibragimov, Askhat Dzhemilev, Usein Molecules Article An efficient method for the synthesis of tetraoxathiaspiroalkanes, tetraoxathiocanes, and hexaoxathiadispiroalkanes was developed by reactions of pentaoxacanes, pentaoxaspiroalkanes, and heptaoxadispiroalkanes with hydrogen sulfide in the presence of a catalyst, Sm(NO(3))(3)·6H(2)O. We found that the synthesized S-containing di- and triperoxides exhibit high cytotoxic activity against Jurkat, K562, U937, and HL60 tumor cultures, and fibroblasts. MDPI 2020-04-18 /pmc/articles/PMC7221664/ /pubmed/32325665 http://dx.doi.org/10.3390/molecules25081874 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Makhmudiyarova, Nataliya
Ishmukhametova, Irina
Dzhemileva, Lilya
D’yakonov, Vladimir
Ibragimov, Askhat
Dzhemilev, Usein
First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides
title First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides
title_full First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides
title_fullStr First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides
title_full_unstemmed First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides
title_short First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides
title_sort first example of catalytic synthesis of cyclic s-containing di- and triperoxides
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7221664/
https://www.ncbi.nlm.nih.gov/pubmed/32325665
http://dx.doi.org/10.3390/molecules25081874
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