C−H Functionalization—Prediction of Selectivity in Iridium(I)‐Catalyzed Hydrogen Isotope Exchange Competition Reactions

An assessment of the C−H activation catalyst [(COD)Ir(IMes)(PPh(3))]PF(6) (COD=1,5‐cyclooctadiene, IMes=1,3‐bis(2,4,6‐trimethylphenyl)imidazol‐2‐ylidene) in the deuteration of phenyl rings containing different functional directing groups is divulged. Competition experiments have revealed a clear ord...

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Detalles Bibliográficos
Autores principales: Valero, Mégane, Kruissink, Thomas, Blass, Jennifer, Weck, Remo, Güssregen, Stefan, Plowright, Alleyn T., Derdau, Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7232431/
https://www.ncbi.nlm.nih.gov/pubmed/31917506
http://dx.doi.org/10.1002/anie.201914220

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7232431/
https://www.ncbi.nlm.nih.gov/pubmed/31917506
http://dx.doi.org/10.1002/anie.201914220

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