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Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa

[Image: see text] We present the adsorption data of CO(2), CH(4), and N(2) ternary mixtures on anthracite from 293.15 to 353.15 K and pressures up to 7 MPa obtained via a volumetric method. The experimental data are given at different conditions, and simple analysis is made. The results show that th...

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Autores principales: Xing, Wanli, Liu, Yifan, Zhang, Wanli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7241004/
https://www.ncbi.nlm.nih.gov/pubmed/32455236
http://dx.doi.org/10.1021/acsomega.0c01083
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author Xing, Wanli
Liu, Yifan
Zhang, Wanli
author_facet Xing, Wanli
Liu, Yifan
Zhang, Wanli
author_sort Xing, Wanli
collection PubMed
description [Image: see text] We present the adsorption data of CO(2), CH(4), and N(2) ternary mixtures on anthracite from 293.15 to 353.15 K and pressures up to 7 MPa obtained via a volumetric method. The experimental data are given at different conditions, and simple analysis is made. The results show that the excess adsorption capacity of the CO(2)/CH(4)/N(2) mixture and its component gases decreases linearly with the increase of temperature for constant composition. The total adsorption capacity is between pure CO(2) and pure N(2) in the entire pressure range. The effect of total pressure on total adsorption capacity is mainly influenced by the CO(2) mole fraction in the feed gas. However, the adsorption capacities of CH(4) and N(2) decrease, and CO(2) presents a maximum with the decrease in total pressure. For the feed gases of 10% CH(4) and 16% CO(2), the total adsorption capacity increases when the ratio of CO(2) and CH(4) increases, respectively, and the increasing magnitudes for 10% CH(4) are larger than that of 16% CO(2). The obtained experimental data are in agreement with the extended three-parameter Ono–Kondo model.
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spelling pubmed-72410042020-05-22 Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa Xing, Wanli Liu, Yifan Zhang, Wanli ACS Omega [Image: see text] We present the adsorption data of CO(2), CH(4), and N(2) ternary mixtures on anthracite from 293.15 to 353.15 K and pressures up to 7 MPa obtained via a volumetric method. The experimental data are given at different conditions, and simple analysis is made. The results show that the excess adsorption capacity of the CO(2)/CH(4)/N(2) mixture and its component gases decreases linearly with the increase of temperature for constant composition. The total adsorption capacity is between pure CO(2) and pure N(2) in the entire pressure range. The effect of total pressure on total adsorption capacity is mainly influenced by the CO(2) mole fraction in the feed gas. However, the adsorption capacities of CH(4) and N(2) decrease, and CO(2) presents a maximum with the decrease in total pressure. For the feed gases of 10% CH(4) and 16% CO(2), the total adsorption capacity increases when the ratio of CO(2) and CH(4) increases, respectively, and the increasing magnitudes for 10% CH(4) are larger than that of 16% CO(2). The obtained experimental data are in agreement with the extended three-parameter Ono–Kondo model. American Chemical Society 2020-05-06 /pmc/articles/PMC7241004/ /pubmed/32455236 http://dx.doi.org/10.1021/acsomega.0c01083 Text en Copyright © 2020 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Xing, Wanli
Liu, Yifan
Zhang, Wanli
Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa
title Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa
title_full Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa
title_fullStr Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa
title_full_unstemmed Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa
title_short Adsorption Characteristics of CO(2)/CH(4)/N(2) Ternary Mixtures on Anthracite from 293.15 to 353.15 K and Pressures Up to 7 MPa
title_sort adsorption characteristics of co(2)/ch(4)/n(2) ternary mixtures on anthracite from 293.15 to 353.15 k and pressures up to 7 mpa
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7241004/
https://www.ncbi.nlm.nih.gov/pubmed/32455236
http://dx.doi.org/10.1021/acsomega.0c01083
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