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Possibility of realizing superionic ice VII in external electric fields of planetary bodies
In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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American Association for the Advancement of Science
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7244312/ https://www.ncbi.nlm.nih.gov/pubmed/32494738 http://dx.doi.org/10.1126/sciadv.aaz2915 |
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author | Futera, Zdenek Tse, John S. English, Niall J. |
author_facet | Futera, Zdenek Tse, John S. English, Niall J. |
author_sort | Futera, Zdenek |
collection | PubMed |
description | In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical studies indicate possible SI prevalence in large-planet mantles (e.g., Uranus and Neptune) and exoplanets. Here, we realize sustainable SI behavior in ice VII by means of externally applied electric fields, using state-of-the-art nonequilibrium ab initio molecular dynamics to witness at first hand the protons’ fluid dance through a dipole-ordered ice VII lattice. We point out the possibility of SI ice VII on Venus, in its strong permanent electric field. |
format | Online Article Text |
id | pubmed-7244312 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Association for the Advancement of Science |
record_format | MEDLINE/PubMed |
spelling | pubmed-72443122020-06-02 Possibility of realizing superionic ice VII in external electric fields of planetary bodies Futera, Zdenek Tse, John S. English, Niall J. Sci Adv Research Articles In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical studies indicate possible SI prevalence in large-planet mantles (e.g., Uranus and Neptune) and exoplanets. Here, we realize sustainable SI behavior in ice VII by means of externally applied electric fields, using state-of-the-art nonequilibrium ab initio molecular dynamics to witness at first hand the protons’ fluid dance through a dipole-ordered ice VII lattice. We point out the possibility of SI ice VII on Venus, in its strong permanent electric field. American Association for the Advancement of Science 2020-05-22 /pmc/articles/PMC7244312/ /pubmed/32494738 http://dx.doi.org/10.1126/sciadv.aaz2915 Text en Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). http://creativecommons.org/licenses/by-nc/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (http://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited. |
spellingShingle | Research Articles Futera, Zdenek Tse, John S. English, Niall J. Possibility of realizing superionic ice VII in external electric fields of planetary bodies |
title | Possibility of realizing superionic ice VII in external electric fields of planetary bodies |
title_full | Possibility of realizing superionic ice VII in external electric fields of planetary bodies |
title_fullStr | Possibility of realizing superionic ice VII in external electric fields of planetary bodies |
title_full_unstemmed | Possibility of realizing superionic ice VII in external electric fields of planetary bodies |
title_short | Possibility of realizing superionic ice VII in external electric fields of planetary bodies |
title_sort | possibility of realizing superionic ice vii in external electric fields of planetary bodies |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7244312/ https://www.ncbi.nlm.nih.gov/pubmed/32494738 http://dx.doi.org/10.1126/sciadv.aaz2915 |
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