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Possibility of realizing superionic ice VII in external electric fields of planetary bodies

In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical...

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Autores principales: Futera, Zdenek, Tse, John S., English, Niall J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7244312/
https://www.ncbi.nlm.nih.gov/pubmed/32494738
http://dx.doi.org/10.1126/sciadv.aaz2915
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author Futera, Zdenek
Tse, John S.
English, Niall J.
author_facet Futera, Zdenek
Tse, John S.
English, Niall J.
author_sort Futera, Zdenek
collection PubMed
description In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical studies indicate possible SI prevalence in large-planet mantles (e.g., Uranus and Neptune) and exoplanets. Here, we realize sustainable SI behavior in ice VII by means of externally applied electric fields, using state-of-the-art nonequilibrium ab initio molecular dynamics to witness at first hand the protons’ fluid dance through a dipole-ordered ice VII lattice. We point out the possibility of SI ice VII on Venus, in its strong permanent electric field.
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spelling pubmed-72443122020-06-02 Possibility of realizing superionic ice VII in external electric fields of planetary bodies Futera, Zdenek Tse, John S. English, Niall J. Sci Adv Research Articles In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII’s importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical studies indicate possible SI prevalence in large-planet mantles (e.g., Uranus and Neptune) and exoplanets. Here, we realize sustainable SI behavior in ice VII by means of externally applied electric fields, using state-of-the-art nonequilibrium ab initio molecular dynamics to witness at first hand the protons’ fluid dance through a dipole-ordered ice VII lattice. We point out the possibility of SI ice VII on Venus, in its strong permanent electric field. American Association for the Advancement of Science 2020-05-22 /pmc/articles/PMC7244312/ /pubmed/32494738 http://dx.doi.org/10.1126/sciadv.aaz2915 Text en Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). http://creativecommons.org/licenses/by-nc/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (http://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.
spellingShingle Research Articles
Futera, Zdenek
Tse, John S.
English, Niall J.
Possibility of realizing superionic ice VII in external electric fields of planetary bodies
title Possibility of realizing superionic ice VII in external electric fields of planetary bodies
title_full Possibility of realizing superionic ice VII in external electric fields of planetary bodies
title_fullStr Possibility of realizing superionic ice VII in external electric fields of planetary bodies
title_full_unstemmed Possibility of realizing superionic ice VII in external electric fields of planetary bodies
title_short Possibility of realizing superionic ice VII in external electric fields of planetary bodies
title_sort possibility of realizing superionic ice vii in external electric fields of planetary bodies
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7244312/
https://www.ncbi.nlm.nih.gov/pubmed/32494738
http://dx.doi.org/10.1126/sciadv.aaz2915
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