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Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters
Here we show how a simple inorganic salt can spontaneously form autocatalytic sets of replicating inorganic molecules that work via molecular recognition based on the {PMo(12)} ≡ [PMo(12)O(40)](3–) Keggin ion, and {Mo(36)} ≡ [H(3)Mo(57)M(6)(NO)(6)O(183)(H(2)O)(18)](22–) cluster. These small clusters...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
National Academy of Sciences
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7245103/ https://www.ncbi.nlm.nih.gov/pubmed/32371490 http://dx.doi.org/10.1073/pnas.1921536117 |