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Syntheses, Reactivities, Characterization, and Crystal Structures of Dipalladium Complexes Containing the 1,3-pyrimidinyl Ligand: Structures of [Pd(PPh(3))(Br)](2)(μ,η(2)-C(4)H(3)N(2))(2), [Pd(Br)](2)(μ,η(2)-Hdppa)(2), and [{Pd(PPh(3))(CH(3)CN)}(2)(μ,η(2)-C(4)H(3)N(2))(2)][BF(4)](2)
In a refluxing chloroform solution, the η(1)-pyrimidinyl {pyrimidinyl = C(4)H(3)N(2)} palladium complex [Pd(PPh(3))(2)(η(1)-C(4)H(3)N(2))(Br)], 1 exhibited intermolecular displacement of two triphenylphosphine ligands to form the doubly bridged η(2)-pyrimidinyl Dipalladium complex [Pd(PPh(3))(Br)](2...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7248739/ https://www.ncbi.nlm.nih.gov/pubmed/32349398 http://dx.doi.org/10.3390/molecules25092035 |