Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine

This review article focused on the innovative procedure for electrophilic fluorination using HF and in situ generation of the required electrophilic species derived from hypervalent iodine compounds. The areas of synthetic application of this approach include fluorination of 1,3-dicarbonyl compounds...

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Detalles Bibliográficos
Autores principales: Han, Jianlin, Butler, Greg, Moriwaki, Hiroki, Konno, Hiroyuki, Soloshonok, Vadim A., Kitamura, Tsugio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7248860/
https://www.ncbi.nlm.nih.gov/pubmed/32366048
http://dx.doi.org/10.3390/molecules25092116
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author Han, Jianlin
Butler, Greg
Moriwaki, Hiroki
Konno, Hiroyuki
Soloshonok, Vadim A.
Kitamura, Tsugio
author_facet Han, Jianlin
Butler, Greg
Moriwaki, Hiroki
Konno, Hiroyuki
Soloshonok, Vadim A.
Kitamura, Tsugio
author_sort Han, Jianlin
collection PubMed
description This review article focused on the innovative procedure for electrophilic fluorination using HF and in situ generation of the required electrophilic species derived from hypervalent iodine compounds. The areas of synthetic application of this approach include fluorination of 1,3-dicarbonyl compounds, aryl-alkyl ketones, styrene derivatives, α,β-unsaturated ketones and alcohols, homoallyl amine and homoallyl alcohol derivatives, 3-butenoic acids and alkynes.
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spelling pubmed-72488602020-06-10 Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine Han, Jianlin Butler, Greg Moriwaki, Hiroki Konno, Hiroyuki Soloshonok, Vadim A. Kitamura, Tsugio Molecules Review This review article focused on the innovative procedure for electrophilic fluorination using HF and in situ generation of the required electrophilic species derived from hypervalent iodine compounds. The areas of synthetic application of this approach include fluorination of 1,3-dicarbonyl compounds, aryl-alkyl ketones, styrene derivatives, α,β-unsaturated ketones and alcohols, homoallyl amine and homoallyl alcohol derivatives, 3-butenoic acids and alkynes. MDPI 2020-04-30 /pmc/articles/PMC7248860/ /pubmed/32366048 http://dx.doi.org/10.3390/molecules25092116 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Han, Jianlin
Butler, Greg
Moriwaki, Hiroki
Konno, Hiroyuki
Soloshonok, Vadim A.
Kitamura, Tsugio
Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
title Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
title_full Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
title_fullStr Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
title_full_unstemmed Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
title_short Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine
title_sort kitamura electrophilic fluorination using hf as a source of fluorine
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7248860/
https://www.ncbi.nlm.nih.gov/pubmed/32366048
http://dx.doi.org/10.3390/molecules25092116
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