Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties

Complexes [(dpp-BIAN)(0)Co(II)I(2)]·MeCN (I) and [(Py)(2)CoI(2)] (II) were synthesized by the reaction between cobalt(II) iodide and 1,2-bis(2,6-diisopropylphenylimino)acenaphthene (dpp-BIAN) or pyridine (Py), respectively. The molecular structures of the complexes were determined by X-ray diffracti...

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Autores principales: Yambulatov, Dmitriy S., Nikolaevskii, Stanislav A., Kiskin, Mikhail A., Magdesieva, Tatiana V., Levitskiy, Oleg A., Korchagin, Denis V., Efimov, Nikolay N., Vasil’ev, Pavel N., Goloveshkin, Alexander S., Sidorov, Alexey A., Eremenko, Igor L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7249109/
https://www.ncbi.nlm.nih.gov/pubmed/32354044
http://dx.doi.org/10.3390/molecules25092054
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author Yambulatov, Dmitriy S.
Nikolaevskii, Stanislav A.
Kiskin, Mikhail A.
Magdesieva, Tatiana V.
Levitskiy, Oleg A.
Korchagin, Denis V.
Efimov, Nikolay N.
Vasil’ev, Pavel N.
Goloveshkin, Alexander S.
Sidorov, Alexey A.
Eremenko, Igor L.
author_facet Yambulatov, Dmitriy S.
Nikolaevskii, Stanislav A.
Kiskin, Mikhail A.
Magdesieva, Tatiana V.
Levitskiy, Oleg A.
Korchagin, Denis V.
Efimov, Nikolay N.
Vasil’ev, Pavel N.
Goloveshkin, Alexander S.
Sidorov, Alexey A.
Eremenko, Igor L.
author_sort Yambulatov, Dmitriy S.
collection PubMed
description Complexes [(dpp-BIAN)(0)Co(II)I(2)]·MeCN (I) and [(Py)(2)CoI(2)] (II) were synthesized by the reaction between cobalt(II) iodide and 1,2-bis(2,6-diisopropylphenylimino)acenaphthene (dpp-BIAN) or pyridine (Py), respectively. The molecular structures of the complexes were determined by X-ray diffraction. The Co(II) ions in both compounds are in a distorted tetrahedral environment (CoN(2)I(2)). The electrochemical behavior of complex I was studied by cyclic voltammetry. Magnetochemical measurements revealed that when an external magnetic field is applied, both compounds exhibit the properties of field-induced single ion magnets.
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spelling pubmed-72491092020-06-10 Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties Yambulatov, Dmitriy S. Nikolaevskii, Stanislav A. Kiskin, Mikhail A. Magdesieva, Tatiana V. Levitskiy, Oleg A. Korchagin, Denis V. Efimov, Nikolay N. Vasil’ev, Pavel N. Goloveshkin, Alexander S. Sidorov, Alexey A. Eremenko, Igor L. Molecules Article Complexes [(dpp-BIAN)(0)Co(II)I(2)]·MeCN (I) and [(Py)(2)CoI(2)] (II) were synthesized by the reaction between cobalt(II) iodide and 1,2-bis(2,6-diisopropylphenylimino)acenaphthene (dpp-BIAN) or pyridine (Py), respectively. The molecular structures of the complexes were determined by X-ray diffraction. The Co(II) ions in both compounds are in a distorted tetrahedral environment (CoN(2)I(2)). The electrochemical behavior of complex I was studied by cyclic voltammetry. Magnetochemical measurements revealed that when an external magnetic field is applied, both compounds exhibit the properties of field-induced single ion magnets. MDPI 2020-04-28 /pmc/articles/PMC7249109/ /pubmed/32354044 http://dx.doi.org/10.3390/molecules25092054 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yambulatov, Dmitriy S.
Nikolaevskii, Stanislav A.
Kiskin, Mikhail A.
Magdesieva, Tatiana V.
Levitskiy, Oleg A.
Korchagin, Denis V.
Efimov, Nikolay N.
Vasil’ev, Pavel N.
Goloveshkin, Alexander S.
Sidorov, Alexey A.
Eremenko, Igor L.
Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
title Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
title_full Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
title_fullStr Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
title_full_unstemmed Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
title_short Complexes of Cobalt(II) Iodide with Pyridine and Redox Active 1,2-Bis(arylimino)acenaphthene: Synthesis, Structure, Electrochemical, and Single Ion Magnet Properties
title_sort complexes of cobalt(ii) iodide with pyridine and redox active 1,2-bis(arylimino)acenaphthene: synthesis, structure, electrochemical, and single ion magnet properties
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7249109/
https://www.ncbi.nlm.nih.gov/pubmed/32354044
http://dx.doi.org/10.3390/molecules25092054
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