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Tuning the Reactivity and Bonding Properties of Metal Square-Planar Complexes by the Substitution(s) on the Trans-Coordinated Pyridine Ring
[Image: see text] The kinetics of the hydration reaction on trans-[Pt(NH(3))(2)(pyrX)Cl](+) (pyr = pyridine) complexes (X = OH(–), Cl(–), F(–), Br(–), NO(2)(–), NH(2), SH(–), CH(3), C≡CH, and DMA) was studied by density functional theory calculations in the gas phase and in water solution described...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7254792/ https://www.ncbi.nlm.nih.gov/pubmed/32478268 http://dx.doi.org/10.1021/acsomega.0c01161 |