Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate

[Image: see text] A quaternary ammonium and titanium codoped phosphotungstate (QA(0.5)Ti(0.5)H(0.5)PW) catalyst was prepared by the ion exchange method and used as a solid acid catalyst for the synthesis of n-butyl oleate. The catalyst was characterized by Fourier transform infrared, elemental analy...

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Autores principales: Zhou, Xi, He, Peng, Zhang, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7254816/
https://www.ncbi.nlm.nih.gov/pubmed/32478242
http://dx.doi.org/10.1021/acsomega.0c00693
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author Zhou, Xi
He, Peng
Zhang, Chao
author_facet Zhou, Xi
He, Peng
Zhang, Chao
author_sort Zhou, Xi
collection PubMed
description [Image: see text] A quaternary ammonium and titanium codoped phosphotungstate (QA(0.5)Ti(0.5)H(0.5)PW) catalyst was prepared by the ion exchange method and used as a solid acid catalyst for the synthesis of n-butyl oleate. The catalyst was characterized by Fourier transform infrared, elemental analyzer, energy-dispersive X-ray spectrometry, Brunauer–Emmett–Teller, scanning electron microscopy, and Hammett indicator methods. QA(0.5)Ti(0.5)H(0.5)PW showed a higher catalytic activity than other phosphotungstate solid acid catalysts reported by literature, and the esterification rate reached 99% under optimized conditions. Moreover, QA(0.5)Ti(0.5)H(0.5)PW exhibited well reusability. An esterification rate of 90.1% was still obtained in the eighth run.
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spelling pubmed-72548162020-05-29 Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate Zhou, Xi He, Peng Zhang, Chao ACS Omega [Image: see text] A quaternary ammonium and titanium codoped phosphotungstate (QA(0.5)Ti(0.5)H(0.5)PW) catalyst was prepared by the ion exchange method and used as a solid acid catalyst for the synthesis of n-butyl oleate. The catalyst was characterized by Fourier transform infrared, elemental analyzer, energy-dispersive X-ray spectrometry, Brunauer–Emmett–Teller, scanning electron microscopy, and Hammett indicator methods. QA(0.5)Ti(0.5)H(0.5)PW showed a higher catalytic activity than other phosphotungstate solid acid catalysts reported by literature, and the esterification rate reached 99% under optimized conditions. Moreover, QA(0.5)Ti(0.5)H(0.5)PW exhibited well reusability. An esterification rate of 90.1% was still obtained in the eighth run. American Chemical Society 2020-05-14 /pmc/articles/PMC7254816/ /pubmed/32478242 http://dx.doi.org/10.1021/acsomega.0c00693 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Zhou, Xi
He, Peng
Zhang, Chao
Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate
title Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate
title_full Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate
title_fullStr Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate
title_full_unstemmed Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate
title_short Codoped Phosphotungstate as an Efficient Heterogeneous Catalyst for the Synthesis of n-Butyl Oleate
title_sort codoped phosphotungstate as an efficient heterogeneous catalyst for the synthesis of n-butyl oleate
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7254816/
https://www.ncbi.nlm.nih.gov/pubmed/32478242
http://dx.doi.org/10.1021/acsomega.0c00693
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AT hepeng codopedphosphotungstateasanefficientheterogeneouscatalystforthesynthesisofnbutyloleate
AT zhangchao codopedphosphotungstateasanefficientheterogeneouscatalystforthesynthesisofnbutyloleate

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