Cargando…

1,n-Bisborylalkanes via Radical Boron Migration

[Image: see text] A systematic study of radical boron migration in diboronate complexes to form synthetically valuable 1,n-bisborylalkanes is reported. The boronate complexes are readily generated by reaction of commercial bis(pinacolato)diboron with alkyl Grignard compounds. C-radical generation at...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Dinghai, Mück-Lichtenfeld, Christian, Studer, Armido
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7259776/ https://www.ncbi.nlm.nih.gov/pubmed/32363871 http://dx.doi.org/10.1021/jacs.0c03058

Ejemplares similares

Radical Aryl Migration from Boron to Carbon
por: Wang, Dinghai, et al.
Publicado: (2021)

Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents
por: Wang, Dinghai, et al.
Publicado: (2019)

Metal‐Free Radical Borylation of Alkyl and Aryl Iodides
por: Cheng, Ying, et al.
Publicado: (2018)

Photocatalytic phosphine-mediated water activation for radical hydrogenation
por: Zhang, Jingjing, et al.
Publicado: (2023)

Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes
por: Wang, Dinghai, et al.
Publicado: (2021)

Remote C−H functionalization using radical translocating arylating groups
por: Friese, Florian W., et al.
Publicado: (2018)

Azodioxy compounds as precursors for C-radicals and their application in thermal styrene difunctionalization
por: Plöger, Stefanie, et al.
Publicado: (2022)

Radical‐Induced 1,2‐Migrations of Boron Ate Complexes
por: Kischkewitz, Marvin, et al.
Publicado: (2020)

Three-component 1,2-carboamination of vinyl boronic esters via amidyl radical induced 1,2-migration
por: You, Cai, et al.
Publicado: (2021)

Transition Metal-Free 1,2-Carboboration of Unactivated Alkenes
por: Cheng, Ying, et al.
Publicado: (2018)

Allylboronic Esters as Acceptors in Radical Addition, Boron 1,2-Migration, and Trapping Cascades
por: Jana, Kalipada, et al.
Publicado: (2022)

Radical Hydrodehalogenation of Aryl Bromides and Chlorides with Sodium Hydride and 1,4‐Dioxane
por: Hokamp, Tobias, et al.
Publicado: (2017)

Stereoselective Lewis base catalyzed formal 1,3-dipolar cycloaddition of azomethine imines with mixed anhydrides
por: Hesping, Lena, et al.
Publicado: (2015)

α-Perfluoroalkyl-β-alkynylation of alkenes via radical alkynyl migration
por: Tang, Xinjun, et al.
Publicado: (2017)

Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration
por: Tang, Xinjun, et al.
Publicado: (2017)

Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration
por: You, Cai, et al.
Publicado: (2020)

1,4-Aryl migration in ketene-derived enolates by a polar-radical-crossover cascade
por: Radhoff, Niklas, et al.
Publicado: (2022)

Synthesis of α‐Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes
por: Gerleve, Carolin, et al.
Publicado: (2018)

New avenues for C–B bond formation via radical intermediates
por: Friese, Florian W., et al.
Publicado: (2019)

Iodine(III) Reagents in Radical Chemistry
por: Wang, Xi, et al.
Publicado: (2017)

Oxindole synthesis via polar–radical crossover of ketene-derived amide enolates in a formal [3 + 2] cycloaddition
por: Radhoff, Niklas, et al.
Publicado: (2022)

Radical boron migration of allylboronic esters
por: Tao, Xiangzhang, et al.
Publicado: (2022)

Regio- and Stereoselective Radical Perfluoroalkyltriflation of Alkynes Using Phenyl(perfluoroalkyl)iodonium Triflates
por: Wang, Xi, et al.
Publicado: (2017)

Catalytic protodeboronation of pinacol boronic esters: formal anti-Markovnikov hydromethylation of alkenes
por: Clausen, Florian, et al.
Publicado: (2019)

Radical 1‐Fluorosulfonyl‐2‐alkynylation of Unactivated Alkenes
por: Frye, Nils Lennart, et al.
Publicado: (2022)

Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis
por: Liu, Kun, et al.
Publicado: (2021)

Decatungstate-catalyzed radical disulfuration through direct C-H functionalization for the preparation of unsymmetrical disulfides
por: Zhang, Jingjing, et al.
Publicado: (2022)

Remote Radical Desaturation of Unactivated C−H Bonds in Amides
por: Xia, Yong, et al.
Publicado: (2021)

Functionalization of α‐C(sp(3))−H Bonds in Amides Using Radical Translocating Arylating Groups
por: Radhoff, Niklas, et al.
Publicado: (2020)

Carboamination of Unactivated Alkenes through Three‐Component Radical Conjugate Addition
por: Jiang, Heng, et al.
Publicado: (2019)

Radical-Polar Crossover Reactions of Dienylboronate Complexes: Synthesis of Functionalized Allylboronic Esters
por: Kischkewitz, Marvin, et al.
Publicado: (2018)

Arynes as Radical Acceptors: TEMPO‐Mediated Cascades Comprising Addition, Cyclization, and Trapping
por: Scherübl, Maximilian, et al.
Publicado: (2020)

Oxy‐Borylenes as Photoreductants: Synthesis and Application in Dehalogenation and Detosylation Reactions
por: Lenz, Philipp, et al.
Publicado: (2022)

Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides
por: Janhsen, Benjamin, et al.
Publicado: (2017)

Remote Site‐Selective Radical C(sp(3))−H Monodeuteration of Amides using D(2)O
por: Wang, Lin, et al.
Publicado: (2021)

The renaissance of organic radical chemistry – deja vu all over again
por: Stephenson, Corey R J, et al.
Publicado: (2013)

Photo-induced trifunctionalization of bromostyrenes via remote radical migration reactions of tetracoordinate boron species
por: Li, Chaokun, et al.
Publicado: (2022)

Selective multifunctionalization of N-heterocyclic carbene boranes via the intermediacy of boron-centered radicals
por: Li, Feng-Xing, et al.
Publicado: (2023)

Geometric E→Z Isomerisation of Alkenyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal anti‐Metallometallation
por: Faßbender, Svenja I., et al.
Publicado: (2019)

Photoinitiated Three-Component α-Perfluoroalkyl-β-heteroarylation of Unactivated Alkenes via Electron Catalysis
por: Zheng, Danqing, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_cbpvb4qbkmqdm16e74g3rqhrrd