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Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine

The asymmetric unit of the title compound, C(23)H(20)N(2)OS, contains one slightly bent mol­ecule. The naphthalene ring system and the thia­zole ring are twisted with respect to each other, making a dihedral angle of 13.69 (10)°; the anisole ring is inclined to the plane of the naphthalene ring syst...

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Detalles Bibliográficos
Autores principales: Sheakh Mohamad, Ropak A., Hamad, Wali M., Aziz, Hashim J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273988/
https://www.ncbi.nlm.nih.gov/pubmed/32523764
http://dx.doi.org/10.1107/S2056989020006611
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author Sheakh Mohamad, Ropak A.
Hamad, Wali M.
Aziz, Hashim J.
author_facet Sheakh Mohamad, Ropak A.
Hamad, Wali M.
Aziz, Hashim J.
author_sort Sheakh Mohamad, Ropak A.
collection PubMed
description The asymmetric unit of the title compound, C(23)H(20)N(2)OS, contains one slightly bent mol­ecule. The naphthalene ring system and the thia­zole ring are twisted with respect to each other, making a dihedral angle of 13.69 (10)°; the anisole ring is inclined to the plane of the naphthalene ring system, the dihedral angle being 14.22 (12)°. In the crystal structure, mol­ecules are linked by C—H⋯π inter­actions, resulting in the formation of sheets parallel to (100). Within the sheets, very weak π–π stacking inter­actions lead to additional stabilization. Hirshfeld surface analysis and fingerprint plots reveal that the cohesion in the crystal structure is dominated by H⋯H (42.5%) and C⋯H/H⋯C (37.2%) contacts.
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spelling pubmed-72739882020-06-09 Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine Sheakh Mohamad, Ropak A. Hamad, Wali M. Aziz, Hashim J. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, C(23)H(20)N(2)OS, contains one slightly bent mol­ecule. The naphthalene ring system and the thia­zole ring are twisted with respect to each other, making a dihedral angle of 13.69 (10)°; the anisole ring is inclined to the plane of the naphthalene ring system, the dihedral angle being 14.22 (12)°. In the crystal structure, mol­ecules are linked by C—H⋯π inter­actions, resulting in the formation of sheets parallel to (100). Within the sheets, very weak π–π stacking inter­actions lead to additional stabilization. Hirshfeld surface analysis and fingerprint plots reveal that the cohesion in the crystal structure is dominated by H⋯H (42.5%) and C⋯H/H⋯C (37.2%) contacts. International Union of Crystallography 2020-05-29 /pmc/articles/PMC7273988/ /pubmed/32523764 http://dx.doi.org/10.1107/S2056989020006611 Text en © Sheakh Mohamad et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Sheakh Mohamad, Ropak A.
Hamad, Wali M.
Aziz, Hashim J.
Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
title Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
title_full Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
title_fullStr Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
title_short Crystal structure and Hirshfeld surface analysis of 4-(naphthalen-2-yl)-N-[(Z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
title_sort crystal structure and hirshfeld surface analysis of 4-(naphthalen-2-yl)-n-[(z)-4-propoxybenzyl­idene]-1,3-thia­zol-2-amine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273988/
https://www.ncbi.nlm.nih.gov/pubmed/32523764
http://dx.doi.org/10.1107/S2056989020006611
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