Cargando…
Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene
The title compounds, 6-cyclopropyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclopropylmethylidene)-1,3-diphenylcyclopenta-1,3-diene], 1, and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-dimethoxynaphthalen-2-yl)methylidene]-1,...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273991/ https://www.ncbi.nlm.nih.gov/pubmed/32523759 http://dx.doi.org/10.1107/S2056989020006441 |
Sumario: | The title compounds, 6-cyclopropyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclopropylmethylidene)-1,3-diphenylcyclopenta-1,3-diene], 1, and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-dimethoxynaphthalen-2-yl)methylidene]-1,3-diphenylcyclopenta-1,3-diene}, 2, were prepared from 1,3-diphenylcyclopentadiene, pyrrolidine, and the corresponding aldehydes in an ethanolic solution. Each structure crystallizes with one molecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C—H⋯C ring interactions as well as C—H⋯O interactions is observed, resulting in the compact packing found in each structure. |
---|