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Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene

The title compounds, 6-cyclo­propyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclo­propyl­methyl­idene)-1,3-di­phen­yl­cyclo­penta-1,3-diene], 1, and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-di­meth­oxy­naphthalen-2-yl)methyl­idene]-1,...

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Detalles Bibliográficos
Autores principales: Brown, Loren C., Iacono, Scott T., Balaich, Gary J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273991/
https://www.ncbi.nlm.nih.gov/pubmed/32523759
http://dx.doi.org/10.1107/S2056989020006441
Descripción
Sumario:The title compounds, 6-cyclo­propyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclo­propyl­methyl­idene)-1,3-di­phen­yl­cyclo­penta-1,3-diene], 1, and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-di­meth­oxy­naphthalen-2-yl)methyl­idene]-1,3-di­phenyl­cyclo­penta-1,3-di­ene}, 2, were prepared from 1,3-di­phenyl­cyclo­penta­diene, pyrrolidine, and the corresponding aldehydes in an ethano­lic solution. Each structure crystallizes with one mol­ecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C—H⋯C ring inter­actions as well as C—H⋯O inter­actions is observed, resulting in the compact packing found in each structure.