Cargando…

Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene

The title compounds, 6-cyclo­propyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclo­propyl­methyl­idene)-1,3-di­phen­yl­cyclo­penta-1,3-diene], 1, and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-di­meth­oxy­naphthalen-2-yl)methyl­idene]-1,...

Descripción completa

Detalles Bibliográficos
Autores principales: Brown, Loren C., Iacono, Scott T., Balaich, Gary J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273991/
https://www.ncbi.nlm.nih.gov/pubmed/32523759
http://dx.doi.org/10.1107/S2056989020006441
_version_ 1783542503434092544
author Brown, Loren C.
Iacono, Scott T.
Balaich, Gary J.
author_facet Brown, Loren C.
Iacono, Scott T.
Balaich, Gary J.
author_sort Brown, Loren C.
collection PubMed
description The title compounds, 6-cyclo­propyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclo­propyl­methyl­idene)-1,3-di­phen­yl­cyclo­penta-1,3-diene], 1, and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-di­meth­oxy­naphthalen-2-yl)methyl­idene]-1,3-di­phenyl­cyclo­penta-1,3-di­ene}, 2, were prepared from 1,3-di­phenyl­cyclo­penta­diene, pyrrolidine, and the corresponding aldehydes in an ethano­lic solution. Each structure crystallizes with one mol­ecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C—H⋯C ring inter­actions as well as C—H⋯O inter­actions is observed, resulting in the compact packing found in each structure.
format Online
Article
Text
id pubmed-7273991
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-72739912020-06-09 Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene Brown, Loren C. Iacono, Scott T. Balaich, Gary J. Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, 6-cyclo­propyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclo­propyl­methyl­idene)-1,3-di­phen­yl­cyclo­penta-1,3-diene], 1, and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-di­meth­oxy­naphthalen-2-yl)methyl­idene]-1,3-di­phenyl­cyclo­penta-1,3-di­ene}, 2, were prepared from 1,3-di­phenyl­cyclo­penta­diene, pyrrolidine, and the corresponding aldehydes in an ethano­lic solution. Each structure crystallizes with one mol­ecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C—H⋯C ring inter­actions as well as C—H⋯O inter­actions is observed, resulting in the compact packing found in each structure. International Union of Crystallography 2020-05-22 /pmc/articles/PMC7273991/ /pubmed/32523759 http://dx.doi.org/10.1107/S2056989020006441 Text en © Brown et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Brown, Loren C.
Iacono, Scott T.
Balaich, Gary J.
Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
title Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
title_full Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
title_fullStr Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
title_full_unstemmed Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
title_short Crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
title_sort crystal structures of 6-cyclo­propyl-1,3-diphenylfulvene and 6-(2,3-di­meth­oxy­naphth­yl)-1,3-di­phenylfulvene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273991/
https://www.ncbi.nlm.nih.gov/pubmed/32523759
http://dx.doi.org/10.1107/S2056989020006441
work_keys_str_mv AT brownlorenc crystalstructuresof6cyclopropyl13diphenylfulveneand623dimethoxynaphthyl13diphenylfulvene
AT iaconoscottt crystalstructuresof6cyclopropyl13diphenylfulveneand623dimethoxynaphthyl13diphenylfulvene
AT balaichgaryj crystalstructuresof6cyclopropyl13diphenylfulveneand623dimethoxynaphthyl13diphenylfulvene