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Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene
The title compounds, 6-cyclopropyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclopropylmethylidene)-1,3-diphenylcyclopenta-1,3-diene], 1, and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-dimethoxynaphthalen-2-yl)methylidene]-1,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273991/ https://www.ncbi.nlm.nih.gov/pubmed/32523759 http://dx.doi.org/10.1107/S2056989020006441 |
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author | Brown, Loren C. Iacono, Scott T. Balaich, Gary J. |
author_facet | Brown, Loren C. Iacono, Scott T. Balaich, Gary J. |
author_sort | Brown, Loren C. |
collection | PubMed |
description | The title compounds, 6-cyclopropyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclopropylmethylidene)-1,3-diphenylcyclopenta-1,3-diene], 1, and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-dimethoxynaphthalen-2-yl)methylidene]-1,3-diphenylcyclopenta-1,3-diene}, 2, were prepared from 1,3-diphenylcyclopentadiene, pyrrolidine, and the corresponding aldehydes in an ethanolic solution. Each structure crystallizes with one molecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C—H⋯C ring interactions as well as C—H⋯O interactions is observed, resulting in the compact packing found in each structure. |
format | Online Article Text |
id | pubmed-7273991 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-72739912020-06-09 Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene Brown, Loren C. Iacono, Scott T. Balaich, Gary J. Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, 6-cyclopropyl-1,3-diphenylfulvene, C(21)H(18), [systematic name: 5-(cyclopropylmethylidene)-1,3-diphenylcyclopenta-1,3-diene], 1, and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene, C(30)H(24)O(2), {systematic name: 5-[(3,4-dimethoxynaphthalen-2-yl)methylidene]-1,3-diphenylcyclopenta-1,3-diene}, 2, were prepared from 1,3-diphenylcyclopentadiene, pyrrolidine, and the corresponding aldehydes in an ethanolic solution. Each structure crystallizes with one molecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C—H⋯C ring interactions as well as C—H⋯O interactions is observed, resulting in the compact packing found in each structure. International Union of Crystallography 2020-05-22 /pmc/articles/PMC7273991/ /pubmed/32523759 http://dx.doi.org/10.1107/S2056989020006441 Text en © Brown et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Brown, Loren C. Iacono, Scott T. Balaich, Gary J. Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
title | Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
title_full | Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
title_fullStr | Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
title_full_unstemmed | Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
title_short | Crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
title_sort | crystal structures of 6-cyclopropyl-1,3-diphenylfulvene and 6-(2,3-dimethoxynaphthyl)-1,3-diphenylfulvene |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273991/ https://www.ncbi.nlm.nih.gov/pubmed/32523759 http://dx.doi.org/10.1107/S2056989020006441 |
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