Cargando…

The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative

In the first reported crystal structure involving the potential ligand N,N′,N′′-tris­(pyridin-2-­yl)benzene-1,3,5-­tricarboxamide, C(24)H(18)N(6)O(3), inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder...

Descripción completa

Detalles Bibliográficos
Autores principales: Senior, Levi, Linden, Anthony
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273992/
https://www.ncbi.nlm.nih.gov/pubmed/32523737
http://dx.doi.org/10.1107/S2056989020005599
_version_ 1783542503671070720
author Senior, Levi
Linden, Anthony
author_facet Senior, Levi
Linden, Anthony
author_sort Senior, Levi
collection PubMed
description In the first reported crystal structure involving the potential ligand N,N′,N′′-tris­(pyridin-2-­yl)benzene-1,3,5-­tricarboxamide, C(24)H(18)N(6)O(3), inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding inter­actions and the benzene ring cores of the mol­ecules act as the rungs of the ladder. Only two of the three amide groups in the mol­ecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds.
format Online
Article
Text
id pubmed-7273992
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-72739922020-06-09 The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative Senior, Levi Linden, Anthony Acta Crystallogr E Crystallogr Commun Research Communications In the first reported crystal structure involving the potential ligand N,N′,N′′-tris­(pyridin-2-­yl)benzene-1,3,5-­tricarboxamide, C(24)H(18)N(6)O(3), inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding inter­actions and the benzene ring cores of the mol­ecules act as the rungs of the ladder. Only two of the three amide groups in the mol­ecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds. International Union of Crystallography 2020-05-01 /pmc/articles/PMC7273992/ /pubmed/32523737 http://dx.doi.org/10.1107/S2056989020005599 Text en © Senior and Linden 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Senior, Levi
Linden, Anthony
The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
title The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
title_full The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
title_fullStr The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
title_full_unstemmed The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
title_short The missing crystal structure in the series of N,N′,N′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
title_sort missing crystal structure in the series of n,n′,n′′-tris­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273992/
https://www.ncbi.nlm.nih.gov/pubmed/32523737
http://dx.doi.org/10.1107/S2056989020005599
work_keys_str_mv AT seniorlevi themissingcrystalstructureintheseriesofnnntrispyridinylbenzene135tricarboxamidesthe2pyridinylderivative
AT lindenanthony themissingcrystalstructureintheseriesofnnntrispyridinylbenzene135tricarboxamidesthe2pyridinylderivative
AT seniorlevi missingcrystalstructureintheseriesofnnntrispyridinylbenzene135tricarboxamidesthe2pyridinylderivative
AT lindenanthony missingcrystalstructureintheseriesofnnntrispyridinylbenzene135tricarboxamidesthe2pyridinylderivative