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The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative
In the first reported crystal structure involving the potential ligand N,N′,N′′-tris(pyridin-2-yl)benzene-1,3,5-tricarboxamide, C(24)H(18)N(6)O(3), intermolecular N—H⋯O hydrogen bonds link the molecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273992/ https://www.ncbi.nlm.nih.gov/pubmed/32523737 http://dx.doi.org/10.1107/S2056989020005599 |
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author | Senior, Levi Linden, Anthony |
author_facet | Senior, Levi Linden, Anthony |
author_sort | Senior, Levi |
collection | PubMed |
description | In the first reported crystal structure involving the potential ligand N,N′,N′′-tris(pyridin-2-yl)benzene-1,3,5-tricarboxamide, C(24)H(18)N(6)O(3), intermolecular N—H⋯O hydrogen bonds link the molecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding interactions and the benzene ring cores of the molecules act as the rungs of the ladder. Only two of the three amide groups in the molecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds. |
format | Online Article Text |
id | pubmed-7273992 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-72739922020-06-09 The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative Senior, Levi Linden, Anthony Acta Crystallogr E Crystallogr Commun Research Communications In the first reported crystal structure involving the potential ligand N,N′,N′′-tris(pyridin-2-yl)benzene-1,3,5-tricarboxamide, C(24)H(18)N(6)O(3), intermolecular N—H⋯O hydrogen bonds link the molecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding interactions and the benzene ring cores of the molecules act as the rungs of the ladder. Only two of the three amide groups in the molecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds. International Union of Crystallography 2020-05-01 /pmc/articles/PMC7273992/ /pubmed/32523737 http://dx.doi.org/10.1107/S2056989020005599 Text en © Senior and Linden 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Senior, Levi Linden, Anthony The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
title | The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
title_full | The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
title_fullStr | The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
title_full_unstemmed | The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
title_short | The missing crystal structure in the series of N,N′,N′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
title_sort | missing crystal structure in the series of n,n′,n′′-tris(pyridinyl)benzene-1,3,5-tricarboxamides: the 2-pyridinyl derivative |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7273992/ https://www.ncbi.nlm.nih.gov/pubmed/32523737 http://dx.doi.org/10.1107/S2056989020005599 |
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