Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline

In the title compound, C(16)H(14)Cl(2)FN(3), the dihedral angle between the two aromatic rings is 64.12 (14)°. The crystal structure is stabilized by a short Cl⋯H contact, C—Cl⋯π and van der Waals inter­actions. The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (33.3...

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Autores principales: Özkaraca, Kadriye, Akkurt, Mehmet, Shikhaliyev, Namiq Q., Askerova, Ulviyya F., Suleymanova, Gulnar T., Shikhaliyeva, Irada M., Bhattarai, Ajaya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7274008/
https://www.ncbi.nlm.nih.gov/pubmed/32523745
http://dx.doi.org/10.1107/S2056989020006106
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author Özkaraca, Kadriye
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Askerova, Ulviyya F.
Suleymanova, Gulnar T.
Shikhaliyeva, Irada M.
Bhattarai, Ajaya
author_facet Özkaraca, Kadriye
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Askerova, Ulviyya F.
Suleymanova, Gulnar T.
Shikhaliyeva, Irada M.
Bhattarai, Ajaya
author_sort Özkaraca, Kadriye
collection PubMed
description In the title compound, C(16)H(14)Cl(2)FN(3), the dihedral angle between the two aromatic rings is 64.12 (14)°. The crystal structure is stabilized by a short Cl⋯H contact, C—Cl⋯π and van der Waals inter­actions. The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (33.3%), Cl⋯H/H⋯Cl (22.9%) and C⋯H/H⋯C (15.5%) inter­actions are the most important contributors towards the crystal packing.
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spelling pubmed-72740082020-06-09 Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline Özkaraca, Kadriye Akkurt, Mehmet Shikhaliyev, Namiq Q. Askerova, Ulviyya F. Suleymanova, Gulnar T. Shikhaliyeva, Irada M. Bhattarai, Ajaya Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(16)H(14)Cl(2)FN(3), the dihedral angle between the two aromatic rings is 64.12 (14)°. The crystal structure is stabilized by a short Cl⋯H contact, C—Cl⋯π and van der Waals inter­actions. The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (33.3%), Cl⋯H/H⋯Cl (22.9%) and C⋯H/H⋯C (15.5%) inter­actions are the most important contributors towards the crystal packing. International Union of Crystallography 2020-05-06 /pmc/articles/PMC7274008/ /pubmed/32523745 http://dx.doi.org/10.1107/S2056989020006106 Text en © Özkaraca et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Özkaraca, Kadriye
Akkurt, Mehmet
Shikhaliyev, Namiq Q.
Askerova, Ulviyya F.
Suleymanova, Gulnar T.
Shikhaliyeva, Irada M.
Bhattarai, Ajaya
Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_full Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_fullStr Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_short Crystal structure and Hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(E)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-N,N-di­methyl­aniline
title_sort crystal structure and hirshfeld surface analysis of 4-{2,2-di­chloro-1-[(e)-(4-fluoro­phen­yl)diazen­yl]ethen­yl}-n,n-di­methyl­aniline
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7274008/
https://www.ncbi.nlm.nih.gov/pubmed/32523745
http://dx.doi.org/10.1107/S2056989020006106
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