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Synthesis of esters of diaminotruxillic bis-amino acids by Pd-mediated photocycloaddition of analogs of the Kaede protein chromophore

The stereoselective synthesis of truxillic bis-amino esters from polyfunctional oxazolones is reported. The reaction of 4-((Z)-arylidene)-2-(E)-styryl-5(4H)-oxazolones 2 with Pd(OAc)(2) resulted in ortho-palladation and the formation of a dinuclear open-book complexes 3 with carboxylate bridges, whe...

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Detalles Bibliográficos
Autores principales: Urriolabeitia, Esteban P, Sánchez, Pablo, Pop, Alexandra, Silvestru, Cristian, Laga, Eduardo, Jiménez, Ana I, Cativiela, Carlos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7277947/
https://www.ncbi.nlm.nih.gov/pubmed/32550926
http://dx.doi.org/10.3762/bjoc.16.98