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Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene
The size-uniformed mesoporous Ag@SiO(2) nanospheres’ catalysts were prepared in one-pot step via reducing AgNO(3) by different types of aldehyde, which could control the size of Ag@SiO(2) NPs and exhibit excellent catalytic activity for the hydrogenation of nitrobenzene. The results showed that the...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7279246/ https://www.ncbi.nlm.nih.gov/pubmed/32375276 http://dx.doi.org/10.3390/nano10050883 |
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author | Zhao, Bonan Dong, Zhipeng Wang, Qiyan Xu, Yisong Zhang, Nanxia Liu, Weixing Lou, Fangning Wang, Yue |
author_facet | Zhao, Bonan Dong, Zhipeng Wang, Qiyan Xu, Yisong Zhang, Nanxia Liu, Weixing Lou, Fangning Wang, Yue |
author_sort | Zhao, Bonan |
collection | PubMed |
description | The size-uniformed mesoporous Ag@SiO(2) nanospheres’ catalysts were prepared in one-pot step via reducing AgNO(3) by different types of aldehyde, which could control the size of Ag@SiO(2) NPs and exhibit excellent catalytic activity for the hydrogenation of nitrobenzene. The results showed that the Ag core size, monitored by different aldehydes with different reducing abilities, together with the ideal monodisperse core-shell mesoporous structure, was quite important to affect its superior catalytic performances. Moreover, the stability of Ag fixed in the core during reaction for 6 h under 2.0 MPa, 140 °C made this type of Ag@SiO(2) catalyst separable and environmentally friendly compared with those conventional homogeneous catalysts and metal NPs catalysts. The best catalyst with smaller Ag cores was prepared by strong reducing agents such as CH(2)O. The conversion of nitrobenzene can reach 99.9%, the selectivity was 100% and the catalyst maintained its activity after several cycles, and thus, it is a useful novel candidate for the production of aniline. |
format | Online Article Text |
id | pubmed-7279246 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-72792462020-06-15 Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene Zhao, Bonan Dong, Zhipeng Wang, Qiyan Xu, Yisong Zhang, Nanxia Liu, Weixing Lou, Fangning Wang, Yue Nanomaterials (Basel) Article The size-uniformed mesoporous Ag@SiO(2) nanospheres’ catalysts were prepared in one-pot step via reducing AgNO(3) by different types of aldehyde, which could control the size of Ag@SiO(2) NPs and exhibit excellent catalytic activity for the hydrogenation of nitrobenzene. The results showed that the Ag core size, monitored by different aldehydes with different reducing abilities, together with the ideal monodisperse core-shell mesoporous structure, was quite important to affect its superior catalytic performances. Moreover, the stability of Ag fixed in the core during reaction for 6 h under 2.0 MPa, 140 °C made this type of Ag@SiO(2) catalyst separable and environmentally friendly compared with those conventional homogeneous catalysts and metal NPs catalysts. The best catalyst with smaller Ag cores was prepared by strong reducing agents such as CH(2)O. The conversion of nitrobenzene can reach 99.9%, the selectivity was 100% and the catalyst maintained its activity after several cycles, and thus, it is a useful novel candidate for the production of aniline. MDPI 2020-05-03 /pmc/articles/PMC7279246/ /pubmed/32375276 http://dx.doi.org/10.3390/nano10050883 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Zhao, Bonan Dong, Zhipeng Wang, Qiyan Xu, Yisong Zhang, Nanxia Liu, Weixing Lou, Fangning Wang, Yue Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene |
title | Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene |
title_full | Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene |
title_fullStr | Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene |
title_full_unstemmed | Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene |
title_short | Highly Efficient Mesoporous Core-Shell Structured Ag@SiO(2) Nanosphere as an Environmentally Friendly Catalyst for Hydrogenation of Nitrobenzene |
title_sort | highly efficient mesoporous core-shell structured ag@sio(2) nanosphere as an environmentally friendly catalyst for hydrogenation of nitrobenzene |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7279246/ https://www.ncbi.nlm.nih.gov/pubmed/32375276 http://dx.doi.org/10.3390/nano10050883 |
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