Simple Fabrication of Transparent, Colorless, and Self-Disinfecting Polyethylene Terephthalate Film via Cold Plasma Treatment

Cross-infection following cross-contamination is a serious social issue worldwide. Pathogens are normally spread by contact with germ-contaminated surfaces. Accordingly, antibacterial surface technologies are urgently needed and have consequently been actively developed in recent years. Among these technologies, biomimetic nanopatterned surfaces that physically kill adhering bacteria have attracted attraction as an effective technological solution to replace toxic chemical disinfectants (biocides). Herein, we introduce a transparent, colorless, and self-disinfecting polyethylene terephthalate (PET) film that mimics the surface structure of the Progomphus obscurus (sanddragon) wing physically killing the attached bacteria. The PET film was partially etched via a 4-min carbon tetrafluoride (CF(4)) plasma treatment. Compared to a flat bare PET film, the plasma-treated film surface exhibited a uniform array structure composed of nanopillars with a 30 nm diameter, 237 nm height, and 75 nm pitch. The plasma-treated PET film showed improvements in optical properties (transmittance and B*) and antibacterial effectiveness over the bare film; the transparency and colorlessness slightly increased, and the antibacterial activity increased from 53.8 to 100% for Staphylococcus aureus, and from 0 to 100% for Escherichia coli. These results demonstrated the feasibility of the CF(4) plasma-treated PET film as a potential antibacterial overcoating with good optical properties.