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Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis

A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximat...

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Autores principales: Gannon, William J. F., Warwick, Michael E. A., Dunnill, Charles W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7281084/
https://www.ncbi.nlm.nih.gov/pubmed/32456208
http://dx.doi.org/10.3390/membranes10050109
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author Gannon, William J. F.
Warwick, Michael E. A.
Dunnill, Charles W.
author_facet Gannon, William J. F.
Warwick, Michael E. A.
Dunnill, Charles W.
author_sort Gannon, William J. F.
collection PubMed
description A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximately half the resistance of a comparable commercial alternative (Zirfon(TM)). Its gas-separation performance was analysed using gas chromatography (GC) at 140 mA cm(−2), where it achieved 99.25% purity at the hydrogen outlet of the electrolyser. This fell to 97.5% under pumped circulation, which highlights that it is sensitive to pressure differentials. Nevertheless, this mixture is still more than a factor two inside the upper flammability limit of hydrogen in oxygen. It is hoped that such a low-cost material may bring entry-level electrolysis to many hitherto discounted applications.
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spelling pubmed-72810842020-06-15 Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis Gannon, William J. F. Warwick, Michael E. A. Dunnill, Charles W. Membranes (Basel) Article A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximately half the resistance of a comparable commercial alternative (Zirfon(TM)). Its gas-separation performance was analysed using gas chromatography (GC) at 140 mA cm(−2), where it achieved 99.25% purity at the hydrogen outlet of the electrolyser. This fell to 97.5% under pumped circulation, which highlights that it is sensitive to pressure differentials. Nevertheless, this mixture is still more than a factor two inside the upper flammability limit of hydrogen in oxygen. It is hoped that such a low-cost material may bring entry-level electrolysis to many hitherto discounted applications. MDPI 2020-05-23 /pmc/articles/PMC7281084/ /pubmed/32456208 http://dx.doi.org/10.3390/membranes10050109 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Gannon, William J. F.
Warwick, Michael E. A.
Dunnill, Charles W.
Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
title Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
title_full Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
title_fullStr Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
title_full_unstemmed Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
title_short Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
title_sort woven stainless-steel mesh as a gas separation membrane for alkaline water-splitting electrolysis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7281084/
https://www.ncbi.nlm.nih.gov/pubmed/32456208
http://dx.doi.org/10.3390/membranes10050109
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