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Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis
A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximat...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7281084/ https://www.ncbi.nlm.nih.gov/pubmed/32456208 http://dx.doi.org/10.3390/membranes10050109 |
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author | Gannon, William J. F. Warwick, Michael E. A. Dunnill, Charles W. |
author_facet | Gannon, William J. F. Warwick, Michael E. A. Dunnill, Charles W. |
author_sort | Gannon, William J. F. |
collection | PubMed |
description | A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximately half the resistance of a comparable commercial alternative (Zirfon(TM)). Its gas-separation performance was analysed using gas chromatography (GC) at 140 mA cm(−2), where it achieved 99.25% purity at the hydrogen outlet of the electrolyser. This fell to 97.5% under pumped circulation, which highlights that it is sensitive to pressure differentials. Nevertheless, this mixture is still more than a factor two inside the upper flammability limit of hydrogen in oxygen. It is hoped that such a low-cost material may bring entry-level electrolysis to many hitherto discounted applications. |
format | Online Article Text |
id | pubmed-7281084 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-72810842020-06-15 Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis Gannon, William J. F. Warwick, Michael E. A. Dunnill, Charles W. Membranes (Basel) Article A 316-grade woven stainless-steel mesh membrane was investigated as a gas-separation membrane for alkaline water-splitting electrolysis. Its resistance was measured using electrochemical impedance spectroscopy (EIS) and linear sweep voltammetry (LSV), with the conclusion that it presented approximately half the resistance of a comparable commercial alternative (Zirfon(TM)). Its gas-separation performance was analysed using gas chromatography (GC) at 140 mA cm(−2), where it achieved 99.25% purity at the hydrogen outlet of the electrolyser. This fell to 97.5% under pumped circulation, which highlights that it is sensitive to pressure differentials. Nevertheless, this mixture is still more than a factor two inside the upper flammability limit of hydrogen in oxygen. It is hoped that such a low-cost material may bring entry-level electrolysis to many hitherto discounted applications. MDPI 2020-05-23 /pmc/articles/PMC7281084/ /pubmed/32456208 http://dx.doi.org/10.3390/membranes10050109 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Gannon, William J. F. Warwick, Michael E. A. Dunnill, Charles W. Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis |
title | Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis |
title_full | Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis |
title_fullStr | Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis |
title_full_unstemmed | Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis |
title_short | Woven Stainless-Steel Mesh as a Gas Separation Membrane for Alkaline Water-Splitting Electrolysis |
title_sort | woven stainless-steel mesh as a gas separation membrane for alkaline water-splitting electrolysis |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7281084/ https://www.ncbi.nlm.nih.gov/pubmed/32456208 http://dx.doi.org/10.3390/membranes10050109 |
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