A Facile Preparation and Energetic Characteristics of the Core/Shell CoFe(2)O(4)/Al Nanowires Thermite Film

In this study, CoFe(2)O(4) is selected for the first time to synthesize CoFe(2)O(4)/Al nanothermite films via an integration of nano-Al with CoFe(2)O(4) nanowires (NWs), which can be prepared through a facile hydrothermal-annealing route. The resulting nanothermite film demonstrates a homogeneous structure and an intense contact between the Al and CoFe(2)O(4) NWs at the nanoscale. In addition, both thermal analysis and laser ignition test reveal the superb energetic performances of the prepared CoFe(2)O(4)/Al NWs nanothermite film. Within different thicknesses of nano-Al for the CoFe(2)O(4)/Al NWs nanothermite films investigated here, the maximum heat output has reached as great as 2100 J·g(−1) at the optimal thickness of 400 nm for deposited Al. Moreover, the fabrication strategy for CoFe(2)O(4)/Al NWs is also easy and suitable for diverse thermite systems based upon other composite metal oxides, such as MnCo(2)O(4) and NiCo(2)O(4). Importantly, this method has the featured advantages of simple operation and compatibility with microsystems, both of which may further facilitate potential applications for functional energetic chips.