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Unraveling the History and Revisiting the Synthesis of Degradable Polystyrene Analogues via Radical Ring-Opening Copolymerization with Cyclic Ketene Acetals

Degradable analogues of polystyrene are synthesized via radical ring-opening (co)polymerization (rROP) between styrene and two cyclic ketene acetals, namely 2-methylene-1,3-dioxepane (MDO) and 5,6-benzo-2-methylene-1,3-dioxepane (BMDO). This approach periodically inserts ester bonds throughout the m...

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Detalles Bibliográficos
Autores principales: Jackson, Alexander W., Reddy Mothe, Srinivasa, Chennamaneni, Lohitha Rao, van Herk, Alexander, Thoniyot, Praveen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7287801/
https://www.ncbi.nlm.nih.gov/pubmed/32438587
http://dx.doi.org/10.3390/ma13102325