Covalent Organic Frameworks: A Promising Materials Platform for Photocatalytic CO(2) Reductions

Covalent organic frameworks (COFs) are a kind of porous crystalline polymeric material. They are constructed by organic module units connected with strong covalent bonds extending in two or three dimensions. COFs possess the advantages of low-density, large specific surface area, high thermal stability, developed pore-structure, long-range order, good crystallinity, and the excellent tunability of the monomer units and the linking reticular chemistry. These features endowed COFs with the ability to be applied in a plethora of applications, ranging from adsorption and separation, sensing, catalysis, optoelectronics, energy storage, mass transport, etc. In this paper, we will review the recent progress of COFs materials applied in photocatalytic CO(2) reduction. The state-of-the-art paragon examples and the current challenges will be discussed in detail. The future direction in this research field will be finally outlooked.