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Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes

In this study, Li(4)Ti(5)O(12) (LTO) electrodes with different types of water-soluble binders are successfully coated upon aluminum foil. Electrodes containing solely sodium alginate (SA) as a binder or a mixed PVDF/carboxymethyl cellulose (CMC) binder show the most stable performance in 1 M LiPF(6)...

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Detalles Bibliográficos
Autores principales: Toigo, Christina, Arbizzani, Catia, Pettinger, Karl-Heinz, Biso, Maurizio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7288146/
https://www.ncbi.nlm.nih.gov/pubmed/32456269
http://dx.doi.org/10.3390/molecules25102443
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author Toigo, Christina
Arbizzani, Catia
Pettinger, Karl-Heinz
Biso, Maurizio
author_facet Toigo, Christina
Arbizzani, Catia
Pettinger, Karl-Heinz
Biso, Maurizio
author_sort Toigo, Christina
collection PubMed
description In this study, Li(4)Ti(5)O(12) (LTO) electrodes with different types of water-soluble binders are successfully coated upon aluminum foil. Electrodes containing solely sodium alginate (SA) as a binder or a mixed PVDF/carboxymethyl cellulose (CMC) binder show the most stable performance in 1 M LiPF(6) in EC/DMC 1:1 in half cell vs. Li, with respect to cycle stability over 100 cycles at 1 C. The electrodes processed with a mixture of PVDF/SA show considerable fading and slightly worse values for rate capability. Each one of the different binders used is eco-friendly, and the whole processing can be performed without the use of organic solvents. Further advantages covering the whole production and recycling process, as well as safety issues during operation, encourage deeper research in this area.
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spelling pubmed-72881462020-06-17 Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes Toigo, Christina Arbizzani, Catia Pettinger, Karl-Heinz Biso, Maurizio Molecules Article In this study, Li(4)Ti(5)O(12) (LTO) electrodes with different types of water-soluble binders are successfully coated upon aluminum foil. Electrodes containing solely sodium alginate (SA) as a binder or a mixed PVDF/carboxymethyl cellulose (CMC) binder show the most stable performance in 1 M LiPF(6) in EC/DMC 1:1 in half cell vs. Li, with respect to cycle stability over 100 cycles at 1 C. The electrodes processed with a mixture of PVDF/SA show considerable fading and slightly worse values for rate capability. Each one of the different binders used is eco-friendly, and the whole processing can be performed without the use of organic solvents. Further advantages covering the whole production and recycling process, as well as safety issues during operation, encourage deeper research in this area. MDPI 2020-05-24 /pmc/articles/PMC7288146/ /pubmed/32456269 http://dx.doi.org/10.3390/molecules25102443 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Toigo, Christina
Arbizzani, Catia
Pettinger, Karl-Heinz
Biso, Maurizio
Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes
title Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes
title_full Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes
title_fullStr Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes
title_full_unstemmed Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes
title_short Study on Different Water-Based Binders for Li(4)Ti(5)O(12) Electrodes
title_sort study on different water-based binders for li(4)ti(5)o(12) electrodes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7288146/
https://www.ncbi.nlm.nih.gov/pubmed/32456269
http://dx.doi.org/10.3390/molecules25102443
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