Metal–Organic Framework-Derived Strategy for Improving Catalytic Performance of a Chromia-Based Catalyst in the Chlorine/Fluorine Exchange Reactions for Unsaturated Fluorocarbons

[Image: see text] Hydrofluoroolefins (HFOs) and cyclic hydrofluorocarbons (c-HFCs) have been the most favored alternatives of the ozone depletion substances; however, because of the poor performance of the present chlorine/fluorine (Cl/F) exchange catalysts, the development and production of HFOs and c-HFCs are hindered. Here, we first report a novel and facile route to fabricate high-performance Cl/F exchange catalysts via a metal–organic framework (MOF) carbonization method. The MOF-derived catalyst not only has high selectivity but also can significantly lower the reaction temperature. Moreover, benefiting from the stable structure and coke-inhibiting ability, the MOF-derived catalyst has a long service life compared with the traditional precipitation method. Furthermore, the nanoscopic MOF-derived catalyst can greatly reduce the Cr dosage, which would help to minimize the risk of Cr contamination.