Cargando…

Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic (Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation

[Image: see text] Recently, chemoselective methods for the hydrogenation of fluorinated, silylated, and borylated arenes have been developed providing direct access to previously unattainable, valuable products. Herein, a comprehensive study on the employed rhodium-cyclic (alkyl)(amino)carbene (CAAC...

Descripción completa

Detalles Bibliográficos
Autores principales:	Moock, Daniel, Wiesenfeldt, Mario P., Freitag, Matthias, Muratsugu, Satoshi, Ikemoto, Satoru, Knitsch, Robert, Schneidewind, Jacob, Baumann, Wolfgang, Schäfer, Andreas H., Timmer, Alexander, Tada, Mizuki, Hansen, Michael Ryan, Glorius, Frank
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7295364/ https://www.ncbi.nlm.nih.gov/pubmed/32551183 http://dx.doi.org/10.1021/acscatal.0c01074

Ejemplares similares

Enantioselective hydrogenation of annulated arenes: controlled formation of multiple stereocenters in adjacent rings
por: Wiesenfeldt, Mario P., et al.
Publicado: (2021)

An Electron‐Rich Cyclic (Alkyl)(Amino)Carbene on Au(111), Ag(111), and Cu(111) Surfaces
por: Bakker, Anne, et al.
Publicado: (2020)

Selective Arene Hydrogenation for Direct Access to Saturated Carbo‐ and Heterocycles
por: Wiesenfeldt, Mario P., et al.
Publicado: (2019)

Rhodium‐Catalyzed C−H Methylation and Alkylation Reactions by Carbene‐Transfer Reactions
por: Empel, Claire, et al.
Publicado: (2022)

Unveiling a key catalytic pocket for the ruthenium NHC-catalysed asymmetric heteroarene hydrogenation
por: Hamza, Andrea, et al.
Publicado: (2021)

Mechanistic insights into rhodium-catalyzed enantioselective allylic alkylation for quaternary stereogenic centers
por: Pareek, Monika, et al.
Publicado: (2020)

Cooperation of N‐Heterocyclic Carbenes on a Gold Surface
por: Amirjalayer, Saeed, et al.
Publicado: (2020)

Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes
por: Kumar Kushvaha, Saroj, et al.
Publicado: (2022)

Rhodium-catalyzed direct alkylation of benzylic amines using alkyl bromides
por: Anschuber, Martin, et al.
Publicado: (2018)

Dimerisation, rhodium complex formation and rearrangements of N-heterocyclic carbenes of indazoles
por: Guan, Zong, et al.
Publicado: (2014)

Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes
por: Azpíroz, Ramón, et al.
Publicado: (2022)

Activation of Ge−H and Sn−H Bonds with N‐Heterocyclic Carbenes and a Cyclic (Alkyl)(amino)carbene
por: Philipp, Michael S. M., et al.
Publicado: (2022)

Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes
por: Romanov, Alexander S., et al.
Publicado: (2015)

The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis
por: Pichon, Delphine, et al.
Publicado: (2019)

Rhodium‐Catalyzed Formylation of Unactivated Alkyl Chlorides to Aldehydes
por: Wang, Peng, et al.
Publicado: (2022)

Catalytic generation of ortho-quinone dimethides via donor/donor rhodium carbenes
por: Gao, Mingchun, et al.
Publicado: (2023)

(Me)CAAC=N(−): A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
por: Goettel, James T., et al.
Publicado: (2020)

Realizing 1,1‐Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin‐2‐ols as a Source of Cyclic (Alkyl)(Amino)Carbenes
por: Das, Ayan, et al.
Publicado: (2022)

Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids
por: Maiti, Avijit, et al.
Publicado: (2022)

Directing group assisted rhodium catalyzed meta-C–H alkynylation of arenes
por: Sasmal, Sheuli, et al.
Publicado: (2022)

A cationic rhodium(I) N-heterocyclic carbene complex isolated as an aqua adduct
por: Huttenstine, Ashley L., et al.
Publicado: (2011)

The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium‐to‐Gold Transmetalation
por: Werlé, Christophe, et al.
Publicado: (2015)

From betaines to anionic N-heterocyclic carbenes. Borane, gold, rhodium, and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer
por: Liu, Ming, et al.
Publicado: (2016)

Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
por: Wang, Guocang, et al.
Publicado: (2019)

Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents
por: Kundu, Subrata, et al.
Publicado: (2019)

Tailoring Carbene–Metal–Amides for Thermally Activated Delayed Fluorescence: A Computationally Guided Study on the Effect of Cyclic (Alkyl)(amino)carbenes
por: Phuoc, Nguyen Le, et al.
Publicado: (2023)

Asymmetric arene hydrogenation: towards sustainability and application
por: Lückemeier, Lukas, et al.
Publicado: (2023)

Catalytic Transfer Hydrogenation of Arenes and Heteroarenes
por: Gelis, Coralie, et al.
Publicado: (2020)

Regioselective Radical Alkylation of Arenes Using Evolved Photoenzymes
por: Page, Claire G., et al.
Publicado: (2023)

Rhodium(III)-catalyzed remote difunctionalization of arenes assisted by a relay directing group
por: Sun, Lincong, et al.
Publicado: (2022)

Iridium/N-heterocyclic carbene-catalyzed C–H borylation of arenes by diisopropylaminoborane
por: Tobisu, Mamoru, et al.
Publicado: (2016)

Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-heterocyclic Carbene or Cyclic(alkyl)(amino)carbene Ligands
por: Grzesiński, Łukasz, et al.
Publicado: (2022)

Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
por: Oldroyd, Nicola L., et al.
Publicado: (2019)

Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes
por: Samuel, Prinson P., et al.
Publicado: (2015)

Influence of N-Substituents on the Adsorption Geometry of OH-Functionalized Chiral N-Heterocyclic Carbenes
por: Dery, Shahar, et al.
Publicado: (2021)

Photocatalytic C–F alkylation; facile access to multifluorinated arenes
por: Singh, A., et al.
Publicado: (2015)

trans-Selective and Switchable Arene Hydrogenation of Phenol Derivatives
por: Wollenburg, Marco, et al.
Publicado: (2020)

Highly Stereoselective Synthesis of Cyclopentanes bearing Four Stereocenters by a Rhodium Carbene–Initiated Domino Sequence
por: Parr, Brendan T., et al.
Publicado: (2014)

Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N‐Heterocyclic Carbenes
por: Ho, Luong Phong, et al.
Publicado: (2021)

α‐Amino‐iso‐Butyric Acid Foldamers Terminated with Rhodium(I) N‐Heterocyclic Carbene Catalysts
por: Tilly, David P., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_l9rkcupuldn5c42g56fpbafnff