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Impact of Defects and Crystal Size on Negative Gas Adsorption in DUT-49 Analyzed by In Situ(129)Xe NMR Spectroscopy

[Image: see text] The origin of crystal-size-dependent adsorption behavior of flexible metal–organic frameworks is increasingly studied. In this contribution, we probe the solid–fluid interactions of DUT-49 crystals of different size by in situ(129)Xe NMR spectroscopy at 200 K. With decreasing size...

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Detalles Bibliográficos
Autores principales: Krause, Simon, Reuter, Florian S., Ehrling, Sebastian, Bon, Volodymyr, Senkovska, Irena, Kaskel, Stefan, Brunner, Eike
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7295370/
https://www.ncbi.nlm.nih.gov/pubmed/32550744
http://dx.doi.org/10.1021/acs.chemmater.0c01059