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Impact of Defects and Crystal Size on Negative Gas Adsorption in DUT-49 Analyzed by In Situ(129)Xe NMR Spectroscopy
[Image: see text] The origin of crystal-size-dependent adsorption behavior of flexible metal–organic frameworks is increasingly studied. In this contribution, we probe the solid–fluid interactions of DUT-49 crystals of different size by in situ(129)Xe NMR spectroscopy at 200 K. With decreasing size...
Autores principales: | Krause, Simon, Reuter, Florian S., Ehrling, Sebastian, Bon, Volodymyr, Senkovska, Irena, Kaskel, Stefan, Brunner, Eike |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2020
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7295370/ https://www.ncbi.nlm.nih.gov/pubmed/32550744 http://dx.doi.org/10.1021/acs.chemmater.0c01059 |
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