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Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
[Image: see text] Owing to increased operating time and Pb, As, and alkali metal poisoning of a catalyst, the activity of the catalyst is lowered. In the present study, we utilized the acetic acid and the traditional sulfuric acid pickling process for regeneration and then performed Brunauer–Emmett–...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7301543/ https://www.ncbi.nlm.nih.gov/pubmed/32566855 http://dx.doi.org/10.1021/acsomega.0c01283 |
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author | Li, Jingxin Zhang, Pan Chen, Lan Zhang, Yajuan Qi, Liqiang |
author_facet | Li, Jingxin Zhang, Pan Chen, Lan Zhang, Yajuan Qi, Liqiang |
author_sort | Li, Jingxin |
collection | PubMed |
description | [Image: see text] Owing to increased operating time and Pb, As, and alkali metal poisoning of a catalyst, the activity of the catalyst is lowered. In the present study, we utilized the acetic acid and the traditional sulfuric acid pickling process for regeneration and then performed Brunauer–Emmett–Teller (BET) specific surface area, denitrification efficiency, scanning electron microscopy, and X-ray fluorescence (XRF) analysis of a fresh catalyst, a deactivated catalyst, and a regenerated catalyst for comparison purposes. The experimental results demonstrated that the removal ratios of Pb, As, Na, and K were 99.2, 98.8, 99.9, and 93.9%, respectively. Compared to the traditional sulfuric acid regeneration technology, the acetic acid regeneration technology eliminates the activated liquid immersion step; therefore, the steps are simpler and efficient for the regeneration of selective catalyst reduction catalysts deactivated by Pb, As, and alkali. The current study provides a new method for the regeneration and application of selective catalyst reduction (SCR) catalysts, which is particularly applicable for regenerating a large number of Pb, As, and alkali-metal poisoned catalysts. |
format | Online Article Text |
id | pubmed-7301543 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-73015432020-06-19 Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals Li, Jingxin Zhang, Pan Chen, Lan Zhang, Yajuan Qi, Liqiang ACS Omega [Image: see text] Owing to increased operating time and Pb, As, and alkali metal poisoning of a catalyst, the activity of the catalyst is lowered. In the present study, we utilized the acetic acid and the traditional sulfuric acid pickling process for regeneration and then performed Brunauer–Emmett–Teller (BET) specific surface area, denitrification efficiency, scanning electron microscopy, and X-ray fluorescence (XRF) analysis of a fresh catalyst, a deactivated catalyst, and a regenerated catalyst for comparison purposes. The experimental results demonstrated that the removal ratios of Pb, As, Na, and K were 99.2, 98.8, 99.9, and 93.9%, respectively. Compared to the traditional sulfuric acid regeneration technology, the acetic acid regeneration technology eliminates the activated liquid immersion step; therefore, the steps are simpler and efficient for the regeneration of selective catalyst reduction catalysts deactivated by Pb, As, and alkali. The current study provides a new method for the regeneration and application of selective catalyst reduction (SCR) catalysts, which is particularly applicable for regenerating a large number of Pb, As, and alkali-metal poisoned catalysts. American Chemical Society 2020-06-07 /pmc/articles/PMC7301543/ /pubmed/32566855 http://dx.doi.org/10.1021/acsomega.0c01283 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Li, Jingxin Zhang, Pan Chen, Lan Zhang, Yajuan Qi, Liqiang Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals |
title | Regeneration of Selective Catalyst Reduction Catalysts
Deactivated by Pb, As, and Alkali Metals |
title_full | Regeneration of Selective Catalyst Reduction Catalysts
Deactivated by Pb, As, and Alkali Metals |
title_fullStr | Regeneration of Selective Catalyst Reduction Catalysts
Deactivated by Pb, As, and Alkali Metals |
title_full_unstemmed | Regeneration of Selective Catalyst Reduction Catalysts
Deactivated by Pb, As, and Alkali Metals |
title_short | Regeneration of Selective Catalyst Reduction Catalysts
Deactivated by Pb, As, and Alkali Metals |
title_sort | regeneration of selective catalyst reduction catalysts
deactivated by pb, as, and alkali metals |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7301543/ https://www.ncbi.nlm.nih.gov/pubmed/32566855 http://dx.doi.org/10.1021/acsomega.0c01283 |
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