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Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals

[Image: see text] Owing to increased operating time and Pb, As, and alkali metal poisoning of a catalyst, the activity of the catalyst is lowered. In the present study, we utilized the acetic acid and the traditional sulfuric acid pickling process for regeneration and then performed Brunauer–Emmett–...

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Autores principales: Li, Jingxin, Zhang, Pan, Chen, Lan, Zhang, Yajuan, Qi, Liqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7301543/
https://www.ncbi.nlm.nih.gov/pubmed/32566855
http://dx.doi.org/10.1021/acsomega.0c01283
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author Li, Jingxin
Zhang, Pan
Chen, Lan
Zhang, Yajuan
Qi, Liqiang
author_facet Li, Jingxin
Zhang, Pan
Chen, Lan
Zhang, Yajuan
Qi, Liqiang
author_sort Li, Jingxin
collection PubMed
description [Image: see text] Owing to increased operating time and Pb, As, and alkali metal poisoning of a catalyst, the activity of the catalyst is lowered. In the present study, we utilized the acetic acid and the traditional sulfuric acid pickling process for regeneration and then performed Brunauer–Emmett–Teller (BET) specific surface area, denitrification efficiency, scanning electron microscopy, and X-ray fluorescence (XRF) analysis of a fresh catalyst, a deactivated catalyst, and a regenerated catalyst for comparison purposes. The experimental results demonstrated that the removal ratios of Pb, As, Na, and K were 99.2, 98.8, 99.9, and 93.9%, respectively. Compared to the traditional sulfuric acid regeneration technology, the acetic acid regeneration technology eliminates the activated liquid immersion step; therefore, the steps are simpler and efficient for the regeneration of selective catalyst reduction catalysts deactivated by Pb, As, and alkali. The current study provides a new method for the regeneration and application of selective catalyst reduction (SCR) catalysts, which is particularly applicable for regenerating a large number of Pb, As, and alkali-metal poisoned catalysts.
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spelling pubmed-73015432020-06-19 Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals Li, Jingxin Zhang, Pan Chen, Lan Zhang, Yajuan Qi, Liqiang ACS Omega [Image: see text] Owing to increased operating time and Pb, As, and alkali metal poisoning of a catalyst, the activity of the catalyst is lowered. In the present study, we utilized the acetic acid and the traditional sulfuric acid pickling process for regeneration and then performed Brunauer–Emmett–Teller (BET) specific surface area, denitrification efficiency, scanning electron microscopy, and X-ray fluorescence (XRF) analysis of a fresh catalyst, a deactivated catalyst, and a regenerated catalyst for comparison purposes. The experimental results demonstrated that the removal ratios of Pb, As, Na, and K were 99.2, 98.8, 99.9, and 93.9%, respectively. Compared to the traditional sulfuric acid regeneration technology, the acetic acid regeneration technology eliminates the activated liquid immersion step; therefore, the steps are simpler and efficient for the regeneration of selective catalyst reduction catalysts deactivated by Pb, As, and alkali. The current study provides a new method for the regeneration and application of selective catalyst reduction (SCR) catalysts, which is particularly applicable for regenerating a large number of Pb, As, and alkali-metal poisoned catalysts. American Chemical Society 2020-06-07 /pmc/articles/PMC7301543/ /pubmed/32566855 http://dx.doi.org/10.1021/acsomega.0c01283 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Li, Jingxin
Zhang, Pan
Chen, Lan
Zhang, Yajuan
Qi, Liqiang
Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
title Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
title_full Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
title_fullStr Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
title_full_unstemmed Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
title_short Regeneration of Selective Catalyst Reduction Catalysts Deactivated by Pb, As, and Alkali Metals
title_sort regeneration of selective catalyst reduction catalysts deactivated by pb, as, and alkali metals
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7301543/
https://www.ncbi.nlm.nih.gov/pubmed/32566855
http://dx.doi.org/10.1021/acsomega.0c01283
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