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Negative cooperativity upon hydrogen bond-stabilized O(2) adsorption in a redox-active metal–organic framework
The design of stable adsorbents capable of selectively capturing dioxygen with a high reversible capacity is a crucial goal in functional materials development. Drawing inspiration from biological O(2) carriers, we demonstrate that coupling metal-based electron transfer with secondary coordination s...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7303157/ https://www.ncbi.nlm.nih.gov/pubmed/32555184 http://dx.doi.org/10.1038/s41467-020-16897-z |