Negative cooperativity upon hydrogen bond-stabilized O(2) adsorption in a redox-active metal–organic framework

The design of stable adsorbents capable of selectively capturing dioxygen with a high reversible capacity is a crucial goal in functional materials development. Drawing inspiration from biological O(2) carriers, we demonstrate that coupling metal-based electron transfer with secondary coordination s...

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Detalles Bibliográficos
Autores principales: Oktawiec, Julia, Jiang, Henry Z. H., Vitillo, Jenny G., Reed, Douglas A., Darago, Lucy E., Trump, Benjamin A., Bernales, Varinia, Li, Harriet, Colwell, Kristen A., Furukawa, Hiroyasu, Brown, Craig M., Gagliardi, Laura, Long, Jeffrey R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7303157/
https://www.ncbi.nlm.nih.gov/pubmed/32555184
http://dx.doi.org/10.1038/s41467-020-16897-z

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