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Synthesis of a Porous C(3)N-Derived Framework with High Yield by Gallic Acid Cross-Linking Using Salt Melts

[Image: see text] Porous carbon/nitrogen frameworks are an emerging class of noble organic materials with a wide range of potential applications. However, the design and controlled synthesis of those materials are still a challenge. Herein, we present the rational design of such a system with high m...

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Detalles Bibliográficos
Autores principales: Tian, Zhihong, Heil, Tobias, Schmidt, Johannes, Cao, Shaokui, Antonietti, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7307830/
https://www.ncbi.nlm.nih.gov/pubmed/32091193
http://dx.doi.org/10.1021/acsami.9b20478
Descripción
Sumario:[Image: see text] Porous carbon/nitrogen frameworks are an emerging class of noble organic materials with a wide range of potential applications. However, the design and controlled synthesis of those materials are still a challenge. Herein, we present the rational design of such a system with high microporosity, specific surface areas of up to 946 m(2) g(–1), and excellent condensation yields. The obtained noble frameworks were used for the delivery of larger organic molecules and changed the melting behavior of some daily drug molecules along their highly polarizable surfaces.