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Unveiling the Delicate Balance of Steric and Dispersion Interactions in Organocatalysis Using High-Level Computational Methods
[Image: see text] High-level quantum electronic structure calculations are used to provide a deep insight into the mechanism and stereocontrolling factors of two recently developed catalytic asymmetric Diels–Alder (DA) reactions of cinnamate esters with cyclopentadiene. The reactions employ two stru...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7307905/ https://www.ncbi.nlm.nih.gov/pubmed/31984734 http://dx.doi.org/10.1021/jacs.9b13725 |