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Pyridine Wingtip in [Pd(Py-tzNHC)(2)](2+) Complex Is a Proton Shuttle in the Catalytic Hydroamination of Alkynes
[Image: see text] The cationic palladium(II) complex 1 of pyridyl-mesoionic carbene ligand catalyzes Markovnikov-selective intermolecular hydroamination between anilines and terminal alkynes into the corresponding imines. The reaction proceeds at room temperature, in the absence of additives, with e...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7308070/ https://www.ncbi.nlm.nih.gov/pubmed/31999464 http://dx.doi.org/10.1021/acs.orglett.0c00203 |