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Deazaflavin reductive photocatalysis involves excited semiquinone radicals

Flavin-mediated photocatalytic oxidations are established in synthetic chemistry. In contrast, their use in reductive chemistry is rare. Deazaflavins with a much lower reduction potential are even better suited for reductive chemistry rendering also deazaflavin semiquinones as strong reductants. How...

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Detalles Bibliográficos
Autores principales:	Graml, Andreas, Neveselý, Tomáš, Jan Kutta, Roger, Cibulka, Radek, König, Burkhard
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7311442/ https://www.ncbi.nlm.nih.gov/pubmed/32576821 http://dx.doi.org/10.1038/s41467-020-16909-y

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