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Proton-Coupled Electron Transfer from Tyrosine in the Interior of a de novo Protein: Mechanisms and Primary Proton Acceptor

[Image: see text] Proton-coupled electron transfer (PCET) from tyrosine produces a neutral tyrosyl radical (Y(•)) that is vital to many catalytic redox reactions. To better understand how the protein environment influences the PCET properties of tyrosine, we have studied the radical formation behavi...

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Detalles Bibliográficos
Autores principales: Nilsen-Moe, Astrid, Reinhardt, Clorice R., Glover, Starla D., Liang, Li, Hammes-Schiffer, Sharon, Hammarström, Leif, Tommos, Cecilia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7315633/
https://www.ncbi.nlm.nih.gov/pubmed/32479070
http://dx.doi.org/10.1021/jacs.0c04655