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Proton-Coupled Electron Transfer from Tyrosine in the Interior of a de novo Protein: Mechanisms and Primary Proton Acceptor
[Image: see text] Proton-coupled electron transfer (PCET) from tyrosine produces a neutral tyrosyl radical (Y(•)) that is vital to many catalytic redox reactions. To better understand how the protein environment influences the PCET properties of tyrosine, we have studied the radical formation behavi...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7315633/ https://www.ncbi.nlm.nih.gov/pubmed/32479070 http://dx.doi.org/10.1021/jacs.0c04655 |