Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics

N‐Benzyl aroyl‐S,N‐ketene acetals can be readily synthesized by condensation of aroyl chlorides and N‐benzyl 2‐methyl benzothiazolium salts in good to excellent yields, yielding a library of 35 chromophores with bright solid‐state emission and aggregation‐induced emission characteristics. Varying th...

Descripción completa

Detalles Bibliográficos
Autores principales: Biesen, Lukas, Nirmalananthan‐Budau, Nithiya, Hoffmann, Katrin, Resch‐Genger, Ute, Müller, Thomas J. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317214/
https://www.ncbi.nlm.nih.gov/pubmed/31990116
http://dx.doi.org/10.1002/anie.201916396
_version_ 1783550577495506944
author Biesen, Lukas
Nirmalananthan‐Budau, Nithiya
Hoffmann, Katrin
Resch‐Genger, Ute
Müller, Thomas J. J.
author_facet Biesen, Lukas
Nirmalananthan‐Budau, Nithiya
Hoffmann, Katrin
Resch‐Genger, Ute
Müller, Thomas J. J.
author_sort Biesen, Lukas
collection PubMed
description N‐Benzyl aroyl‐S,N‐ketene acetals can be readily synthesized by condensation of aroyl chlorides and N‐benzyl 2‐methyl benzothiazolium salts in good to excellent yields, yielding a library of 35 chromophores with bright solid‐state emission and aggregation‐induced emission characteristics. Varying the substituent from electron‐donating to electron‐withdrawing enables the tuning of the solid‐state emission color from deep blue to red.
format Online
Article
Text
id pubmed-7317214
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-73172142020-06-30 Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics Biesen, Lukas Nirmalananthan‐Budau, Nithiya Hoffmann, Katrin Resch‐Genger, Ute Müller, Thomas J. J. Angew Chem Int Ed Engl Communications N‐Benzyl aroyl‐S,N‐ketene acetals can be readily synthesized by condensation of aroyl chlorides and N‐benzyl 2‐methyl benzothiazolium salts in good to excellent yields, yielding a library of 35 chromophores with bright solid‐state emission and aggregation‐induced emission characteristics. Varying the substituent from electron‐donating to electron‐withdrawing enables the tuning of the solid‐state emission color from deep blue to red. John Wiley and Sons Inc. 2020-03-10 2020-06-15 /pmc/articles/PMC7317214/ /pubmed/31990116 http://dx.doi.org/10.1002/anie.201916396 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Biesen, Lukas
Nirmalananthan‐Budau, Nithiya
Hoffmann, Katrin
Resch‐Genger, Ute
Müller, Thomas J. J.
Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics
title Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics
title_full Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics
title_fullStr Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics
title_full_unstemmed Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics
title_short Solid‐State Emissive Aroyl‐S,N‐Ketene Acetals with Tunable Aggregation‐Induced Emission Characteristics
title_sort solid‐state emissive aroyl‐s,n‐ketene acetals with tunable aggregation‐induced emission characteristics
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317214/
https://www.ncbi.nlm.nih.gov/pubmed/31990116
http://dx.doi.org/10.1002/anie.201916396
work_keys_str_mv AT biesenlukas solidstateemissivearoylsnketeneacetalswithtunableaggregationinducedemissioncharacteristics
AT nirmalananthanbudaunithiya solidstateemissivearoylsnketeneacetalswithtunableaggregationinducedemissioncharacteristics
AT hoffmannkatrin solidstateemissivearoylsnketeneacetalswithtunableaggregationinducedemissioncharacteristics
AT reschgengerute solidstateemissivearoylsnketeneacetalswithtunableaggregationinducedemissioncharacteristics
AT mullerthomasjj solidstateemissivearoylsnketeneacetalswithtunableaggregationinducedemissioncharacteristics

Ejemplares similares