Cargando…

Formal C−H Carboxylation of Unactivated Arenes

A formal C−H carboxylation of unactivated arenes using CO(2) in green solvents is described. The present strategy combines a sterically controlled Ir‐catalyzed C−H borylation followed by a Cu‐catalyzed carboxylation of the in situ generated organoboronates. The reaction is highly regioselective for...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gevorgyan, Ashot, Hopmann, Kathrin H., Bayer, Annette
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317471/ https://www.ncbi.nlm.nih.gov/pubmed/32003869 http://dx.doi.org/10.1002/chem.202000515

Ejemplares similares

Exploration of New Biomass‐Derived Solvents: Application to Carboxylation Reactions
por: Gevorgyan, Ashot, et al.
Publicado: (2020)

Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights
por: Gevorgyan, Ashot, et al.
Publicado: (2019)

Regio- and stereoselective oxidation of unactivated C–H bonds with Rhodococcus rhodochrous
por: O’Reilly, Elaine, et al.
Publicado: (2012)

Direct C(sp(2))–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
por: Kim, Daeun, et al.
Publicado: (2020)

Asymmetric Catalytic Friedel–Crafts Reactions of Unactivated Arenes
por: Brunen, Sebastian, et al.
Publicado: (2023)

Factors Controlling the Aluminum(I)‐meta‐Selective C−H Activation in Arenes
por: Cabrera‐Trujillo, Jorge Juan, et al.
Publicado: (2021)

Author Correction: Direct C(sp(2))–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
por: Kim, Daeun, et al.
Publicado: (2020)

Small organic molecules with tailored structures: initiators in the transition-metal-free C–H arylation of unactivated arenes
por: Liu, Zhenghui, et al.
Publicado: (2020)

Photocatalytic C−H Azolation of Arenes Using Heterogeneous Carbon Nitride in Batch and Flow
por: Wen, Zhenghui, et al.
Publicado: (2021)

BNN-1,3-dipoles: isolation and intramolecular cycloaddition with unactivated arenes
por: Guo, Rui, et al.
Publicado: (2020)

NMR analysis of t‐butyl‐catalyzed deuterium exchange at unactivated arene localities
por: Stack, Douglas E., et al.
Publicado: (2016)

Light-induced metal-free transformations of unactivated pyridotriazoles
por: Zhang, Ziyan, et al.
Publicado: (2019)

Iridium/N-heterocyclic carbene-catalyzed C–H borylation of arenes by diisopropylaminoborane
por: Tobisu, Mamoru, et al.
Publicado: (2016)

Selective cleavage of unactivated arene ring C–C bonds by iridium: key roles of benzylic C–H activation and metal–metal cooperativity
por: Tian, Yancong, et al.
Publicado: (2021)

Non‐Heme‐Iron‐Mediated Selective Halogenation of Unactivated Carbon−Hydrogen Bonds
por: Bleher, Katharina, et al.
Publicado: (2021)

Metal‐Free Twofold Electrochemical C−H Amination of Activated Arenes: Application to Medicinally Relevant Precursor Synthesis
por: Wesenberg, Lars J., et al.
Publicado: (2020)

Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis
por: Yatham, Veera Reddy, et al.
Publicado: (2019)

Cu(II) carboxylate arene C─H functionalization: Tuning for nonradical pathways
por: Kong, Fanji, et al.
Publicado: (2022)

Reduced Arene Complexes of Scandium
por: Ghana, Priyabrata, et al.
Publicado: (2020)

Pd-catalyzed formal Mizoroki–Heck coupling of unactivated alkyl chlorides
por: Lee, Geun Seok, et al.
Publicado: (2021)

Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity
por: Hooper, Thomas N., et al.
Publicado: (2018)

Chirality Transfer in Gold(I)-Catalysed Direct Allylic Etherifications of Unactivated Alcohols: Experimental and Computational Study
por: Barker, Graeme, et al.
Publicado: (2015)

Palladium-catalyzed picolinamide-directed iodination of remote ortho-C−H bonds of arenes: Synthesis of tetrahydroquinolines
por: Nack, William A, et al.
Publicado: (2016)

Rhodium Indenyl NHC and Fluorenyl‐Tethered NHC Half‐Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C−H Borylation of Arenes and Alkanes
por: Evans, Kieren J., et al.
Publicado: (2021)

Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes
por: Li, Xiaojuan, et al.
Publicado: (2021)

Scalable, Electrochemical Oxidation of Unactivated C–H Bonds
por: Kawamata, Yu, et al.
Publicado: (2017)

Arene Selectivity by a Flexible Coordination Polymer Host
por: Wright, James S., et al.
Publicado: (2016)

Scandium Reduced Arene Complex: Protonation and Reaction with Azobenzene
por: Ghana, Priyabrata, et al.
Publicado: (2021)

Rapid Iododeboronation with and without Gold Catalysis: Application to Radiolabelling of Arenes
por: Webster, Stacey, et al.
Publicado: (2017)

Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO(2)
por: Sun, Guo-Quan, et al.
Publicado: (2021)

Remote Radical Desaturation of Unactivated C−H Bonds in Amides
por: Xia, Yong, et al.
Publicado: (2021)

Site-Selective Functionalization of Unactivated Allylic C–H Bonds via Direct Deprotonation with KTMP: Application to the Formal Total Synthesis of (+)-Artemisinin from Amorphadiene
por: Clanton, Nicholas A., et al.
Publicado: (2023)

Gold-catalyzed formal [4π + 2π]-cycloadditions of propiolate derivatives with unactivated nitriles
por: Karad, Somnath Narayan, et al.
Publicado: (2015)

Chiral Perylene Bisimide Dyes by Interlocked Arene Substituents in the Bay Area
por: Renner, Rebecca, et al.
Publicado: (2021)

Carboxylic Acid Directed γ-Lactonization of Unactivated Primary C–H Bonds Catalyzed by Mn Complexes: Application to Stereoselective Natural Product Diversification
por: Call, Arnau, et al.
Publicado: (2022)

Hydrogenation of unactivated enamines to tertiary amines: rhodium complexes of fluorinated phosphines give marked improvements in catalytic activity
por: Tin, Sergey, et al.
Publicado: (2015)

Synthesis of Core‐Shell Magnetic Supramolecular Nanocatalysts based on Amino‐Functionalized Calix[4]arenes for the Synthesis of 4H‐Chromenes by Ultrasonic Waves
por: Eivazzadeh‐Keihan, Reza, et al.
Publicado: (2020)

Photocatalytic trifluoromethoxylation of arenes and heteroarenes in continuous-flow
por: Nyuchev, Alexander V, et al.
Publicado: (2020)

Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes
por: Tran, Ba L., et al.
Publicado: (2014)

Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds
por: Barsu, Nagaraju, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_5s4ipcpob9695ko2cmcbkrodjl