Synthesis of a Counteranion‐Stabilized Bis(silylium) Ion

The preparation of a molecule with two alkyl‐tethered silylium‐ion sites from the corresponding bis(hydrosilanes) by two‐fold hydride abstraction is reported. The length of the conformationally flexible alkyl bridge is crucial as otherwise the hydride abstraction stops at the stage of a cyclic bissi...

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Detalles Bibliográficos
Autores principales: Wu, Qian, Roy, Avijit, Wang, Guoqiang, Irran, Elisabeth, Klare, Hendrik F. T., Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317492/
https://www.ncbi.nlm.nih.gov/pubmed/32216163
http://dx.doi.org/10.1002/anie.202003799

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317492/
https://www.ncbi.nlm.nih.gov/pubmed/32216163
http://dx.doi.org/10.1002/anie.202003799

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