Exceptional Substrate Diversity in Oxygenation Reactions Catalyzed by a Bis(μ‐oxo) Copper Complex

The enzyme tyrosinase contains a reactive side‐on peroxo dicopper(II) center as catalytically active species in C−H oxygenation reactions. The tyrosinase activity of the isomeric bis(μ‐oxo) dicopper(III) form has been discussed controversially. The synthesis of bis(μ‐oxo) dicopper(III) species [Cu(2...

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Detalles Bibliográficos
Autores principales: Paul, Melanie, Teubner, Melissa, Grimm‐Lebsanft, Benjamin, Golchert, Christiane, Meiners, Yannick, Senft, Laura, Keisers, Kristina, Liebhäuser, Patricia, Rösener, Thomas, Biebl, Florian, Buchenau, Sören, Naumova, Maria, Murzin, Vadim, Krug, Roxanne, Hoffmann, Alexander, Pietruszka, Jörg, Ivanović‐Burmazović, Ivana, Rübhausen, Michael, Herres‐Pawlis, Sonja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317579/
https://www.ncbi.nlm.nih.gov/pubmed/32104930
http://dx.doi.org/10.1002/chem.202000664

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