Cargando…

π‐Complexes of Diborynes with Main Group Atoms

We present herein an in‐depth study of complexes in which a molecule containing a boron‐boron triple bond is bound to tellurate cations. The analysis allows the description of these salts as true π complexes between the B−B triple bond and the tellurium center. These complexes thus extend the well‐k...

Descripción completa

Detalles Bibliográficos
Autores principales:	Ewing, William C., Dellermann, Theresa, Angel Wong, Y. T., Mattock, James D., Vargas, Alfredo, Bryce, David L., Dewhurst, Rian D., Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317709/ https://www.ncbi.nlm.nih.gov/pubmed/32207211 http://dx.doi.org/10.1002/asia.202000185

Ejemplares similares

Mild synthesis of diboryldiborenes by diboration of B–B triple bonds
por: Brückner, Tobias, et al.
Publicado: (2019)

Towards the catalytic activation of inert small molecules by main-group ambiphiles
por: Dewhurst, Rian D., et al.
Publicado: (2020)

A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl
por: Härterich, Marcel, et al.
Publicado: (2023)

Spying on the boron–boron triple bond using spin–spin coupling measured from (11)B solid-state NMR spectroscopy
por: Perras, Frédéric A., et al.
Publicado: (2015)

Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors
por: Heß, Merlin, et al.
Publicado: (2021)

Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clusters
por: Braunschweig, Holger, et al.
Publicado: (2016)

Isolation of diborenes and their 90°-twisted diradical congeners
por: Böhnke, Julian, et al.
Publicado: (2018)

{N′,N′′-Bis[2,6-bis(1-methylethyl)phenyl]-N,N-dimethylguanidinato-κ(2) N′,N′′}dibromidoborane
por: Braunschweig, Holger, et al.
Publicado: (2010)

Dicyclohexyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine–dichlorophenylborane
por: Braunschweig, Holger, et al.
Publicado: (2009)

III-defined concepts in chemistry: rigid force constants vs. compliance constants as bond strength descriptors for the triple bond in diboryne
por: Grunenberg, Jörg
Publicado: (2015)

Controlled Synthesis of Oligomers Containing Main‐Chain B(sp(2))‐B(sp(2)) Bonds
por: Schorr, Fabian, et al.
Publicado: (2021)

Preshower detector for π+π− hadronic atom studies
por: Pentia, M, et al.
Publicado: (2009)

Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules
por: Dhara, Debabrata, et al.
Publicado: (2022)

Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity
por: Auerhammer, Dominic, et al.
Publicado: (2018)

Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?
por: Fantuzzi, Felipe, et al.
Publicado: (2022)

Stable Actinide π Complexes of a Neutral 1,4‐Diborabenzene
por: Paprocki, Valerie, et al.
Publicado: (2020)

Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum
por: Braunschweig, Holger, et al.
Publicado: (2015)

Balancing Donor‐Acceptor and Dispersion Effects in Heavy Main Group Element π Interactions: Effect of Substituents on the Pnictogen⋅⋅⋅π Arene Interaction
por: Krasowska, Małgorzata, et al.
Publicado: (2019)

trans‐Selective Insertional Dihydroboration of a cis‐Diborene: Synthesis of Linear sp(3)‐sp(2)‐sp(3)‐Triboranes and Subsequent Cationization
por: Schmidt, Uwe, et al.
Publicado: (2019)

Zinc‐[7]helicenocyanine and Its Discrete π‐Stacked Homochiral Dimer
por: Zhang, Fangyuan, et al.
Publicado: (2021)

Planar Cyclopenten‐4‐yl Cations: Highly Delocalized π Aromatics Stabilized by Hyperconjugation
por: Nees, Samuel, et al.
Publicado: (2020)

Boron: Its Role in Energy‐Related Processes and Applications
por: Huang, Zhenguo, et al.
Publicado: (2020)

Adducts of the Parent Boraphosphaketene H(2)BPCO and their Decarbonylative Insertion Chemistry
por: Hagspiel, Stephan, et al.
Publicado: (2021)

Diphosphino‐Functionalized 1,8‐Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes
por: Cui, Jingjing, et al.
Publicado: (2021)

The estimation of production rates of $π^+ K^−, π^− K^+$ and $π^+π^−$ atoms in proton-nucleus interactions at 24 and 450 GeV/c
por: Gorchakov, O, et al.
Publicado: (2016)

A constructive way to calculate a yield of $π^+π^ −$-atoms from the Be target
por: Zhabitsky, M.
Publicado: (2019)

Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor
por: Auerhammer, Dominic, et al.
Publicado: (2017)

Tetraiododiborane(4) (B(2)I(4)) is a Polymer Based on sp(3) Boron in the Solid State
por: Muessig, Jonas H., et al.
Publicado: (2020)

Isolation of Neutral, Mono‐, and Dicationic B(2)P(2) Rings by Diphosphorus Addition to a Boron−Boron Triple Bond
por: Brückner, Tobias, et al.
Publicado: (2021)

Boron‐ versus Nitrogen‐Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2‐Aza‐1,4‐diborabutatrienes
por: Gärtner, Annalena, et al.
Publicado: (2021)

Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species
por: Dhara, Debabrata, et al.
Publicado: (2022)

Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes
por: Lenczyk, Carsten, et al.
Publicado: (2019)

Twisting versus Delocalization in CAAC‐ and NHC‐Stabilized Boron‐Based Biradicals: The Roles of Sterics and Electronics
por: Schmid, Paul, et al.
Publicado: (2021)

Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials
por: Bachmann, Jonas, et al.
Publicado: (2022)

Resonances in pp¯ → ηπ+π−π+π− at rest
por: Anisovich, A V, et al.
Publicado: (2001)

Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning
por: Narsaria, Ayush K., et al.
Publicado: (2020)

Isolation and Reactivity of an Antiaromatic s‐Block Metal Compound
por: Roy, Dipak Kumar, et al.
Publicado: (2020)

Study of the Y-π, K-π AND π-π interactions
por: Franzini, P., et al.
Publicado: (1961)

Coupled channel analysis of proton-antiproton annihilation into π0π0π0, π0ηη and π0π0η
por: Amsler, C, et al.
Publicado: (1995)

Updated DIRAC spectrometer at CERN PS for the investigation of ππ and πK atoms
por: Adeva, B, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_0d2qnqk1sikthup19hghjcfbb2