La(3)B(6)O(13)(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO(4) Tetrahedra

La(3)B(6)O(13)(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P2(1) (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner‐ as well as edge‐sharing BO(4)...

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Detalles Bibliográficos
Autores principales: Fuchs, Birgit, Heymann, Gunter, Wang, Xuefei, Tudi, Abudukadi, Bayarjargal, Lkhamsuren, Siegel, Renée, Schmutzler, Adrian, Senker, Jürgen, Joachim‐Mrosko, Bastian, Saxer, Andreas, Yang, Zhihua, Pan, Shilie, Huppertz, Hubert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317773/
https://www.ncbi.nlm.nih.gov/pubmed/31944426
http://dx.doi.org/10.1002/chem.201905419
Descripción
Sumario:La(3)B(6)O(13)(OH) was obtained by a high‐pressure/high‐temperature experiment at 6 GPa and 1673 K. The compound crystallizes in the space group P2(1) (no. 4) with the lattice parameters a=4.785(2), b=12.880(4), c=7.433(3) Å, and β=90.36(10)°, and is built up of corner‐ as well as edge‐sharing BO(4) tetrahedra. It represents the first acentric high‐pressure borate containing these B(2)O(6) entities. The compound develops borate layers of „sechser“‐rings with the La(3+) cations positioned between the layers. Single‐crystal and powder X‐ray diffraction, vibrational and MAS NMR spectroscopy, second‐harmonic generation (SHG) and thermoanalytical measurements, as well as computational methods were used to affirm the proposed structure and the B(2)O(6) entities.

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