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Desymmetrization of Dicationic Diboranes by Isomerization Catalyzed by a Nucleophile

Cationic monoboranes exhibit a rich chemistry. By constrast, only a few cationic diboranes are known, that all are symmetrically substituted. In this work, the first unsymmetrically substituted dicationic diboranes, featuring sp(2)–sp(2)‐hybridized boron atoms, are reported. The compounds are formed...

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Detalles Bibliográficos
Autores principales: Schön, Florian, Greb, Lutz, Kaifer, Elisabeth, Himmel, Hans‐Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317786/
https://www.ncbi.nlm.nih.gov/pubmed/32181953
http://dx.doi.org/10.1002/anie.202001640