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A Photochemical Organocatalytic Strategy for the α‐Alkylation of Ketones by using Radicals
Reported herein is a visible‐light‐mediated radical approach to the α‐alkylation of ketones. This method exploits the ability of a nucleophilic organocatalyst to generate radicals upon S(N)2‐based activation of alkyl halides and blue light irradiation. The resulting open‐shell intermediates are then...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317845/ https://www.ncbi.nlm.nih.gov/pubmed/32053279 http://dx.doi.org/10.1002/anie.201915814 |