Selective ortho‐Functionalization of Adamantylarenes Enabled by Dispersion and an Air‐Stable Palladium(I) Dimer

Contrary to the general belief that Pd‐catalyzed cross‐coupling at sites of severe steric hindrance are disfavored, we herein show that the oxidative addition to C−Br ortho to an adamantyl group is as favored as the corresponding adamantyl‐free system due to attractive dispersion forces. This enable...

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Detalles Bibliográficos
Autores principales: Kalvet, Indrek, Deckers, Kristina, Funes‐Ardoiz, Ignacio, Magnin, Guillaume, Sperger, Theresa, Kremer, Marius, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317867/
https://www.ncbi.nlm.nih.gov/pubmed/32065717
http://dx.doi.org/10.1002/anie.202001326

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317867/
https://www.ncbi.nlm.nih.gov/pubmed/32065717
http://dx.doi.org/10.1002/anie.202001326

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