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Isolation and Structural Characterization of Eightfold Protonated Octacyanometalates [M(CNH)(8)](4+) (M=Mo(IV), W(IV)) from Superacids
Octacyanometalates K(4)[Mo(CN)(8)] and K(4)[W(CN)(8)] are completely protonated in superacidic mixtures of anhydrous hydrogen fluoride and antimony pentafluoride. The resulting hydrogen isocyanide complexes [Mo(CNH)(8)](4+) [SbF(6)](−) (4) and [W(CNH)(8)](4+) [SbF(6)](−) (4) are the first examples o...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7317926/ https://www.ncbi.nlm.nih.gov/pubmed/32207865 http://dx.doi.org/10.1002/anie.202002366 |